Role of host distortion in the intercalation process

E. V. Vakarin; J. P. Badiali; M. D. Levi; D. Aurbach

Role of host distortion in the intercalation process

E. V. Vakarin
, J. P. Badiali
, M. D. Levi
, D. Aurbach

Sorbonne Université

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

Based on a distortive lattice gas model we have investigated the intercalation of ions into a host material. It is shown that an effective potential for the ions results from the intercalation-induced distortion of the host. This interaction induces a distinct peak in the current-concentration diagram. The peak reveals a droplet formation around the distorted host domains. Theoretical results agree with experimental values for Li_xTiS₂. The ionic permselectivity effect is found to play a prominent role for the electrochemical intercalation.

Original language	English
Article number	014304
Pages (from-to)	143041-143046
Number of pages	6
Journal	Physical Review B-Condensed Matter
Volume	63
Issue number	1
State	Published - 2001

Cite this

@article{824e9c3ad9284d689634a56fb723828d,

title = "Role of host distortion in the intercalation process",

abstract = "Based on a distortive lattice gas model we have investigated the intercalation of ions into a host material. It is shown that an effective potential for the ions results from the intercalation-induced distortion of the host. This interaction induces a distinct peak in the current-concentration diagram. The peak reveals a droplet formation around the distorted host domains. Theoretical results agree with experimental values for LixTiS2. The ionic permselectivity effect is found to play a prominent role for the electrochemical intercalation.",

author = "Vakarin, \{E. V.\} and Badiali, \{J. P.\} and Levi, \{M. D.\} and D. Aurbach",

year = "2001",

language = "אנגלית",

volume = "63",

pages = "143041--143046",

journal = "Physical Review B-Condensed Matter",

issn = "0163-1829",

publisher = "American Institute of Physics",

number = "1",

}

TY - JOUR

T1 - Role of host distortion in the intercalation process

AU - Vakarin, E. V.

AU - Badiali, J. P.

AU - Levi, M. D.

AU - Aurbach, D.

PY - 2001

Y1 - 2001

N2 - Based on a distortive lattice gas model we have investigated the intercalation of ions into a host material. It is shown that an effective potential for the ions results from the intercalation-induced distortion of the host. This interaction induces a distinct peak in the current-concentration diagram. The peak reveals a droplet formation around the distorted host domains. Theoretical results agree with experimental values for LixTiS2. The ionic permselectivity effect is found to play a prominent role for the electrochemical intercalation.

AB - Based on a distortive lattice gas model we have investigated the intercalation of ions into a host material. It is shown that an effective potential for the ions results from the intercalation-induced distortion of the host. This interaction induces a distinct peak in the current-concentration diagram. The peak reveals a droplet formation around the distorted host domains. Theoretical results agree with experimental values for LixTiS2. The ionic permselectivity effect is found to play a prominent role for the electrochemical intercalation.

UR - https://www.scopus.com/pages/publications/0035121497

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:0035121497

SN - 0163-1829

VL - 63

SP - 143041

EP - 143046

JO - Physical Review B-Condensed Matter

JF - Physical Review B-Condensed Matter

IS - 1

M1 - 014304

ER -

Role of host distortion in the intercalation process

Abstract

Other files and links

Fingerprint

Cite this