Role of host distortion in the intercalation process

E. V. Vakarin; J. P. Badiali; M. D. Levi; D. Aurbach

Role of host distortion in the intercalation process

E. V. Vakarin, J. P. Badiali, M. D. Levi, D. Aurbach

Sorbonne Université

Research output: Contribution to journal › Article › peer-review

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Abstract

Based on a distortive lattice gas model we have investigated the intercalation of ions into a host material. It is shown that an effective potential for the ions results from the intercalation-induced distortion of the host. This interaction induces a distinct peak in the current-concentration diagram. The peak reveals a droplet formation around the distorted host domains. Theoretical results agree with experimental values for Li_xTiS₂. The ionic permselectivity effect is found to play a prominent role for the electrochemical intercalation.

Original language	English
Article number	014304
Pages (from-to)	143041-143046
Number of pages	6
Journal	Physical Review B - Condensed Matter and Materials Physics
Volume	63
Issue number	1
State	Published - 2001

Cite this

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Role of host distortion in the intercalation process

Abstract

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