Abstract
An analysis of the capacitance curves of a polycrystalline electrode under the conditions of the specific adsorption of ions has been carried out in the framework of the model of ″independent electrodes″ . It is shown that in solutions with a sufficiently high ionic strength the virial adsorption isotherm with a correction for the diffuse electrical double layer formally describes the laws of the specific adsorption of ions in a polycrystalline electrode, but with values for the adsorption parameters differing significantly from those of the faces.
| Original language | English |
|---|---|
| Pages (from-to) | 1060-1065 |
| Number of pages | 6 |
| Journal | Soviet electrochemistry |
| Volume | 18 |
| Issue number | 9 |
| State | Published - 1982 |