ROLE OF CRYSTALLOGRAPHIC HETEROGENEITY IN THE CALCULATION OF THE SPECIFIC ADSORPTION OF IONS ON A POLYCRYSTALLINE ELECTRODE WITH THE USE OF A MIXED ELECTROLYTE WITH A CONSTANT IONIC STRENGTH.

M. D. Levi; B. B. Damaskin; I. A. Bagotskaya

ROLE OF CRYSTALLOGRAPHIC HETEROGENEITY IN THE CALCULATION OF THE SPECIFIC ADSORPTION OF IONS ON A POLYCRYSTALLINE ELECTRODE WITH THE USE OF A MIXED ELECTROLYTE WITH A CONSTANT IONIC STRENGTH.

M. D. Levi, B. B. Damaskin, I. A. Bagotskaya

Israel National Research Center for Electrochemical Propulsion

Research output: Contribution to journal › Article › peer-review

Abstract

An analysis of the capacitance curves of a polycrystalline electrode under the conditions of the specific adsorption of ions has been carried out in the framework of the model of ″independent electrodes″ . It is shown that in solutions with a sufficiently high ionic strength the virial adsorption isotherm with a correction for the diffuse electrical double layer formally describes the laws of the specific adsorption of ions in a polycrystalline electrode, but with values for the adsorption parameters differing significantly from those of the faces.

Original language	English
Pages (from-to)	1060-1065
Number of pages	6
Journal	Soviet electrochemistry
Volume	18
Issue number	9
State	Published - 1982

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title = "ROLE OF CRYSTALLOGRAPHIC HETEROGENEITY IN THE CALCULATION OF THE SPECIFIC ADSORPTION OF IONS ON A POLYCRYSTALLINE ELECTRODE WITH THE USE OF A MIXED ELECTROLYTE WITH A CONSTANT IONIC STRENGTH.",

abstract = "An analysis of the capacitance curves of a polycrystalline electrode under the conditions of the specific adsorption of ions has been carried out in the framework of the model of ″independent electrodes″ . It is shown that in solutions with a sufficiently high ionic strength the virial adsorption isotherm with a correction for the diffuse electrical double layer formally describes the laws of the specific adsorption of ions in a polycrystalline electrode, but with values for the adsorption parameters differing significantly from those of the faces.",

author = "Levi, {M. D.} and Damaskin, {B. B.} and Bagotskaya, {I. A.}",

year = "1982",

language = "אנגלית",

volume = "18",

pages = "1060--1065",

journal = "Soviet electrochemistry",

issn = "0038-5387",

number = "9",

}

ROLE OF CRYSTALLOGRAPHIC HETEROGENEITY IN THE CALCULATION OF THE SPECIFIC ADSORPTION OF IONS ON A POLYCRYSTALLINE ELECTRODE WITH THE USE OF A MIXED ELECTROLYTE WITH A CONSTANT IONIC STRENGTH. / Levi, M. D.; Damaskin, B. B.; Bagotskaya, I. A.
In: Soviet electrochemistry, Vol. 18, No. 9, 1982, p. 1060-1065.

Research output: Contribution to journal › Article › peer-review

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AU - Levi, M. D.

AU - Damaskin, B. B.

AU - Bagotskaya, I. A.

PY - 1982

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N2 - An analysis of the capacitance curves of a polycrystalline electrode under the conditions of the specific adsorption of ions has been carried out in the framework of the model of ″independent electrodes″ . It is shown that in solutions with a sufficiently high ionic strength the virial adsorption isotherm with a correction for the diffuse electrical double layer formally describes the laws of the specific adsorption of ions in a polycrystalline electrode, but with values for the adsorption parameters differing significantly from those of the faces.

AB - An analysis of the capacitance curves of a polycrystalline electrode under the conditions of the specific adsorption of ions has been carried out in the framework of the model of ″independent electrodes″ . It is shown that in solutions with a sufficiently high ionic strength the virial adsorption isotherm with a correction for the diffuse electrical double layer formally describes the laws of the specific adsorption of ions in a polycrystalline electrode, but with values for the adsorption parameters differing significantly from those of the faces.

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ROLE OF CRYSTALLOGRAPHIC HETEROGENEITY IN THE CALCULATION OF THE SPECIFIC ADSORPTION OF IONS ON A POLYCRYSTALLINE ELECTRODE WITH THE USE OF A MIXED ELECTROLYTE WITH A CONSTANT IONIC STRENGTH.

Abstract

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