ROLE OF CRYSTALLOGRAPHIC HETEROGENEITY IN THE CALCULATION OF THE SPECIFIC ADSORPTION OF IONS ON A POLYCRYSTALLINE ELECTRODE WITH THE USE OF A MIXED ELECTROLYTE WITH A CONSTANT IONIC STRENGTH.

M. D. Levi, B. B. Damaskin, I. A. Bagotskaya

Research output: Contribution to journalArticlepeer-review

Abstract

An analysis of the capacitance curves of a polycrystalline electrode under the conditions of the specific adsorption of ions has been carried out in the framework of the model of ″independent electrodes″ . It is shown that in solutions with a sufficiently high ionic strength the virial adsorption isotherm with a correction for the diffuse electrical double layer formally describes the laws of the specific adsorption of ions in a polycrystalline electrode, but with values for the adsorption parameters differing significantly from those of the faces.

Original languageEnglish
Pages (from-to)1060-1065
Number of pages6
JournalSoviet electrochemistry
Volume18
Issue number9
StatePublished - 1982

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