Ring Opening of Aziridine Phosphonates. Correlation of Structure, Nuclear Magnetic Resonance Spectra, and Reactivity

Alfred Hassner, James E. Galle

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

The ring opening of several dimethyl N-aziridinylphosphonates 3 with Cl2 and HCl was studied. The reaction was found to be stereospecific and in most cases regiospecific. Conformational preferences in these compounds could be correlated with 1,3 P-H (PNCCH) coupling constants and with reactivity in ring opening.

Original languageEnglish
Pages (from-to)2273-2276
Number of pages4
JournalJournal of Organic Chemistry
Volume41
Issue number13
DOIs
StatePublished - 1 Jun 1976
Externally publishedYes

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