Revisiting borylanilines: Unique solid-state structures and insight into photophysical properties

Pagidi Sudhakar; Sanjoy Mukherjee; Pakkirisamy Thilagar

doi:10.1021/om301197f

Revisiting borylanilines: Unique solid-state structures and insight into photophysical properties

Pagidi Sudhakar, Sanjoy Mukherjee, Pakkirisamy Thilagar

Indian Institute of Science Bangalore

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

The structure and photophysical properties of two known borylanilines, 4-(dimesitylboryl)aniline (1) and 4-(dimesitylboryl)-3,5-dimethylaniline (2), have been investigated. 1 and 2 have similar donor and acceptor centers but differ in their molecular conformations. Compounds 1 and 2 have been structurally characterized, and they exhibit a rare form of intermolecular N-H- - -π electrostatic interactions. The structure and photophysical properties of 1 and 2 are discussed in the context of computational results.

Original language	English
Pages (from-to)	3129-3133
Number of pages	5
Journal	Organometallics
Volume	32
Issue number	10
DOIs	https://doi.org/10.1021/om301197f
State	Published - 24 May 2013
Externally published	Yes

Access to Document

10.1021/om301197f

Cite this

@article{66f444a07d48479b87f8489cbb0a25c9,

title = "Revisiting borylanilines: Unique solid-state structures and insight into photophysical properties",

abstract = "The structure and photophysical properties of two known borylanilines, 4-(dimesitylboryl)aniline (1) and 4-(dimesitylboryl)-3,5-dimethylaniline (2), have been investigated. 1 and 2 have similar donor and acceptor centers but differ in their molecular conformations. Compounds 1 and 2 have been structurally characterized, and they exhibit a rare form of intermolecular N-H- - -π electrostatic interactions. The structure and photophysical properties of 1 and 2 are discussed in the context of computational results.",

author = "Pagidi Sudhakar and Sanjoy Mukherjee and Pakkirisamy Thilagar",

year = "2013",

month = may,

day = "24",

doi = "10.1021/om301197f",

language = "אנגלית",

volume = "32",

pages = "3129--3133",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "10",

}

TY - JOUR

T1 - Revisiting borylanilines

T2 - Unique solid-state structures and insight into photophysical properties

AU - Sudhakar, Pagidi

AU - Mukherjee, Sanjoy

AU - Thilagar, Pakkirisamy

PY - 2013/5/24

Y1 - 2013/5/24

N2 - The structure and photophysical properties of two known borylanilines, 4-(dimesitylboryl)aniline (1) and 4-(dimesitylboryl)-3,5-dimethylaniline (2), have been investigated. 1 and 2 have similar donor and acceptor centers but differ in their molecular conformations. Compounds 1 and 2 have been structurally characterized, and they exhibit a rare form of intermolecular N-H- - -π electrostatic interactions. The structure and photophysical properties of 1 and 2 are discussed in the context of computational results.

AB - The structure and photophysical properties of two known borylanilines, 4-(dimesitylboryl)aniline (1) and 4-(dimesitylboryl)-3,5-dimethylaniline (2), have been investigated. 1 and 2 have similar donor and acceptor centers but differ in their molecular conformations. Compounds 1 and 2 have been structurally characterized, and they exhibit a rare form of intermolecular N-H- - -π electrostatic interactions. The structure and photophysical properties of 1 and 2 are discussed in the context of computational results.

UR - https://www.scopus.com/pages/publications/84878168022

U2 - 10.1021/om301197f

DO - 10.1021/om301197f

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:84878168022

SN - 0276-7333

VL - 32

SP - 3129

EP - 3133

JO - Organometallics

JF - Organometallics

IS - 10

ER -

Revisiting borylanilines: Unique solid-state structures and insight into photophysical properties

Abstract

Access to Document

Other files and links

Fingerprint

Cite this