Relations between timescales of stochastic thermodynamic observables

Erez Aghion, Jason R. Green

Research output: Contribution to journalArticlepeer-review

Abstract

Any real physical process that produces entropy, dissipates energy as heat, or generates mechanical work must do so on a finite timescale. Recently derived thermodynamic speed limits place bounds on these observables using intrinsic timescales of the process. Here, we derive relationships for the thermodynamic speeds for any composite stochastic observable in terms of the timescales of its individual components. From these speed limits, we find bounds on thermal efficiency of stochastic processes exchanging energy as heat and work and bound the rate of entropy change in a system with entropy production and flow. Using the time set by an external clock, we find bounds on the first time to reach any value for the entropy production. As an illustration, we compute these bounds for Brownian particles diffusing in space subject to a constant-temperature heat bath and a time-dependent external force.

Original languageEnglish
Pages (from-to)270-292
Number of pages23
JournalJournal of Non-Equilibrium Thermodynamics
Volume48
Issue number4
DOIs
StatePublished - 2023
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2023 Walter de Gruyter GmbH. All rights reserved.

Funding

Research funding: This material is based upon work supported by the National Science Foundation under Grant No. 1856250.

FundersFunder number
National Science Foundation1856250

    Keywords

    • Langevin processes
    • master equation
    • nonequilibrium statistical mechanics
    • stochastic thermodynamics
    • thermodynamic speed limits

    Fingerprint

    Dive into the research topics of 'Relations between timescales of stochastic thermodynamic observables'. Together they form a unique fingerprint.

    Cite this