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Regularized Boltzmann-Gibbs statistics for a Brownian particle in a nonconfining field

  • Lucianno Defaveri
  • , Celia Anteneodo
  • , David A. Kessler
  • , Eli Barkai
  • Pontifícia Universidade Católica do Rio de Janeiro
  • Institute of Science and Technology for Complex Systems

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

We consider an overdamped Brownian particle subject to an asymptotically flat potential with a trap of depth U0 around the origin. When the temperature is small compared to the trap depth (ζ=kBT/U01), there exists a range of timescales over which physical observables remain practically constant. This range can be very long, of the order of the Arrhenius factor e1/ζ. For these quasiequilibrium states, the usual Boltzmann-Gibbs recipe does not work since the partition function is divergent due to the flatness of the potential at long distances. However, we show that the standard Boltzmann-Gibbs statistical framework and thermodynamic relations can still be applied through proper regularization. This can be a valuable tool for the analysis of metastability in the nonconfining potential fields that characterize a vast number of systems.

Original languageEnglish
Article number043088
JournalPhysical Review Research
Volume2
Issue number4
DOIs
StatePublished - Oct 2020

Bibliographical note

Publisher Copyright:
© 2020 authors. Published by the American Physical Society.

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