Abstract
We consider an overdamped Brownian particle subject to an asymptotically flat potential with a trap of depth U0 around the origin. When the temperature is small compared to the trap depth (ζ=kBT/U01), there exists a range of timescales over which physical observables remain practically constant. This range can be very long, of the order of the Arrhenius factor e1/ζ. For these quasiequilibrium states, the usual Boltzmann-Gibbs recipe does not work since the partition function is divergent due to the flatness of the potential at long distances. However, we show that the standard Boltzmann-Gibbs statistical framework and thermodynamic relations can still be applied through proper regularization. This can be a valuable tool for the analysis of metastability in the nonconfining potential fields that characterize a vast number of systems.
| Original language | English |
|---|---|
| Article number | 043088 |
| Journal | Physical Review Research |
| Volume | 2 |
| Issue number | 4 |
| DOIs | |
| State | Published - Oct 2020 |
Bibliographical note
Publisher Copyright:© 2020 authors. Published by the American Physical Society.
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