TY - JOUR
T1 - Regularized Boltzmann-Gibbs statistics for a Brownian particle in a nonconfining field
AU - Defaveri, Lucianno
AU - Anteneodo, Celia
AU - Kessler, David A.
AU - Barkai, Eli
N1 - Publisher Copyright:
© 2020 authors. Published by the American Physical Society.
PY - 2020/10
Y1 - 2020/10
N2 - We consider an overdamped Brownian particle subject to an asymptotically flat potential with a trap of depth U0 around the origin. When the temperature is small compared to the trap depth (ζ=kBT/U01), there exists a range of timescales over which physical observables remain practically constant. This range can be very long, of the order of the Arrhenius factor e1/ζ. For these quasiequilibrium states, the usual Boltzmann-Gibbs recipe does not work since the partition function is divergent due to the flatness of the potential at long distances. However, we show that the standard Boltzmann-Gibbs statistical framework and thermodynamic relations can still be applied through proper regularization. This can be a valuable tool for the analysis of metastability in the nonconfining potential fields that characterize a vast number of systems.
AB - We consider an overdamped Brownian particle subject to an asymptotically flat potential with a trap of depth U0 around the origin. When the temperature is small compared to the trap depth (ζ=kBT/U01), there exists a range of timescales over which physical observables remain practically constant. This range can be very long, of the order of the Arrhenius factor e1/ζ. For these quasiequilibrium states, the usual Boltzmann-Gibbs recipe does not work since the partition function is divergent due to the flatness of the potential at long distances. However, we show that the standard Boltzmann-Gibbs statistical framework and thermodynamic relations can still be applied through proper regularization. This can be a valuable tool for the analysis of metastability in the nonconfining potential fields that characterize a vast number of systems.
UR - http://www.scopus.com/inward/record.url?scp=85099952047&partnerID=8YFLogxK
U2 - 10.1103/PhysRevResearch.2.043088
DO - 10.1103/PhysRevResearch.2.043088
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SN - 2643-1564
VL - 2
JO - Physical Review Research
JF - Physical Review Research
IS - 4
M1 - 043088
ER -