Regio- and stereospecific synthesis of functionalized divinyl selenides

Samuel Braverman; Ranjan Jana; Marina Cherkinsky; Hugo E. Gottlieb; Milon Sprecher

doi:10.1055/s-2007-991051

Regio- and stereospecific synthesis of functionalized divinyl selenides

Samuel Braverman, Ranjan Jana, Marina Cherkinsky, Hugo E. Gottlieb, Milon Sprecher

Department of Chemistry

Bar-Ilan University

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Symmetrical Z,Z-bis(1-hydroxymethyl-2-chlorovinyl) selenides have been obtained in high yields by regio- and stereospecific addition of selenium dichloride to propargylic alcohols. Presumably, the hydroxyl group plays an important role in the regio- and stereospecific addition.

Original language	English
Pages (from-to)	2663-2666
Number of pages	4
Journal	Synlett
Issue number	17
DOIs	https://doi.org/10.1055/s-2007-991051
State	Published - 16 Oct 2007

Keywords

Alkynes
Divinyl diselenides
Divinyl selenides
Electrophilic addition
Regioselectivity
Selenium
Stereoselectivity

Access to Document

10.1055/s-2007-991051

Cite this

@article{d66741cff92b425f929faa2c9d9a7b61,

title = "Regio- and stereospecific synthesis of functionalized divinyl selenides",

abstract = "Symmetrical Z,Z-bis(1-hydroxymethyl-2-chlorovinyl) selenides have been obtained in high yields by regio- and stereospecific addition of selenium dichloride to propargylic alcohols. Presumably, the hydroxyl group plays an important role in the regio- and stereospecific addition.",

keywords = "Alkynes, Divinyl diselenides, Divinyl selenides, Electrophilic addition, Regioselectivity, Selenium, Stereoselectivity",

author = "Samuel Braverman and Ranjan Jana and Marina Cherkinsky and Gottlieb, {Hugo E.} and Milon Sprecher",

year = "2007",

month = oct,

day = "16",

doi = "10.1055/s-2007-991051",

language = "אנגלית",

pages = "2663--2666",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "17",

}

TY - JOUR

T1 - Regio- and stereospecific synthesis of functionalized divinyl selenides

AU - Braverman, Samuel

AU - Jana, Ranjan

AU - Cherkinsky, Marina

AU - Gottlieb, Hugo E.

AU - Sprecher, Milon

PY - 2007/10/16

Y1 - 2007/10/16

N2 - Symmetrical Z,Z-bis(1-hydroxymethyl-2-chlorovinyl) selenides have been obtained in high yields by regio- and stereospecific addition of selenium dichloride to propargylic alcohols. Presumably, the hydroxyl group plays an important role in the regio- and stereospecific addition.

AB - Symmetrical Z,Z-bis(1-hydroxymethyl-2-chlorovinyl) selenides have been obtained in high yields by regio- and stereospecific addition of selenium dichloride to propargylic alcohols. Presumably, the hydroxyl group plays an important role in the regio- and stereospecific addition.

KW - Alkynes

KW - Divinyl diselenides

KW - Divinyl selenides

KW - Electrophilic addition

KW - Regioselectivity

KW - Selenium

KW - Stereoselectivity

UR - http://www.scopus.com/inward/record.url?scp=35748986158&partnerID=8YFLogxK

U2 - 10.1055/s-2007-991051

DO - 10.1055/s-2007-991051

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:35748986158

SN - 0936-5214

SP - 2663

EP - 2666

JO - Synlett

JF - Synlett

IS - 17

ER -

Regio- and stereospecific synthesis of functionalized divinyl selenides

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this