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Reductive nitrosation of peptides ligated to high-valent metal cations

  • Dror Shamir
  • , Israel Zilbermann
  • , Eric Maimon
  • , Gary Gellerman
  • , Haim Cohen
  • , Dan Meyerstein
  • Ben-Gurion University of the Negev
  • Ariel University

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

NO reacts with MIII-(glycylglycylglycine), M = Fe; Ni and Cu, to form the terminal N-nitrosated peptide complex. This reaction proceeds by a radical mechanism.

Original languageEnglish
Pages (from-to)5029-5031
Number of pages3
JournalEuropean Journal of Inorganic Chemistry
Issue number32
DOIs
StatePublished - 2007
Externally publishedYes

Keywords

  • High-valent transition metals
  • NO
  • Nitrosation
  • Peptides

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