TY - JOUR
T1 - Reactivities of organic halides, proton donors and olefins in DMSO towards electrochemically generated radical ions
AU - Margel, Shlomo
AU - Levy, Moshe
PY - 1974/10/25
Y1 - 1974/10/25
N2 - The rates of reaction of the radical ions of diethyl fumarate, ethyl cinnamate, stilbene and anthracene, with some organic halides, proton donors and olefins, were measured by cyclic voltammetry. A linear correlation was found between the logarithm of the rate constants and ΔE, the difference in half-wave potential between the electroactive compound and the reactant. Water was an exception, its reactivity is discussed in terms of the charge distribution of the ions.
AB - The rates of reaction of the radical ions of diethyl fumarate, ethyl cinnamate, stilbene and anthracene, with some organic halides, proton donors and olefins, were measured by cyclic voltammetry. A linear correlation was found between the logarithm of the rate constants and ΔE, the difference in half-wave potential between the electroactive compound and the reactant. Water was an exception, its reactivity is discussed in terms of the charge distribution of the ions.
UR - http://www.scopus.com/inward/record.url?scp=0343474853&partnerID=8YFLogxK
U2 - 10.1016/S0022-0728(74)80332-3
DO - 10.1016/S0022-0728(74)80332-3
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AN - SCOPUS:0343474853
SN - 0022-0728
VL - 56
SP - 259
EP - 267
JO - Journal of Electroanalytical Chemistry
JF - Journal of Electroanalytical Chemistry
IS - 2
ER -