Abstract
The mechanism of dehalogenation was investigated in reactions between alkyl radicals and metal powders immersed in aqueous solutions. Radicals were obtained in the presence of an iron powder using radiochemical techniques. It was demonstrated that radicals enter into relatively fast reactions with metallic particles immersed in aqueous solutions and also in solutions of other solvents. It was stated that the variety of mechanisms responsible for the decomposition of the intermediate products formed could be significant in catalytic processes.
| Original language | English |
|---|---|
| Pages (from-to) | 115-118 |
| Number of pages | 4 |
| Journal | Glass Physics and Chemistry |
| Volume | 31 |
| Issue number | 1 |
| DOIs | |
| State | Published - Jan 2005 |
| Externally published | Yes |
Bibliographical note
Funding Information:This work was supported by the Plan Nacional of I+D+I 2008–2011; the Instituto de Salud Carlos III–Subdirección General of Eval-uación and Fomento de la Investigación [grant numbers FIS PI14/00872, FIS PI14/00638, PI16/02057, PI17/01024, PI17/01010]; co-granted by the FEDER (European Regional Development Funds), the ISCIII-RETIC REDinREN RD016/0009 FEDER Funds, the Fundación Renal Iñigo Álvarez de Toledo (FRIAT) and the Comunidad de Madrid CIFRA2 B2017/BMD-3686.
Funding Information:
This work was supported by the Plan Nacional of I+D+I 2008-2011; the Instituto de Salud Carlos III-Subdirecci?n General of Evaluaci?n and Fomento de la Investigaci?n [grant numbers FIS PI14/00872, FIS PI14/00638, PI16/02057, PI17/01024, PI17/01010]; co-granted by the FEDER (European Regional Development Funds), the ISCIII-RETIC REDinREN RD016/0009 FEDER Funds, the Fundaci?n Renal I?igo ?lvarez de Toledo (FRIAT) and the Comunidad de Madrid CIFRA2 B2017/BMD-3686.