TY - JOUR
T1 - Reaction of transition metal carbonyls with heterocyclic systems. V. The reaction of Fe2(CO)9 with bicyclic 1,2-oxazine compounds
AU - Becker, Y.
AU - Eisenstadt, A.
AU - Shvo, Y.
PY - 1978/7/25
Y1 - 1978/7/25
N2 - A study of the reactions of Fe2(CO)9 towards the {A figure is presented} bond has extended 9-phenyl-9-aza-8-oxabicyclo[3.2.2.]nona-6-ene (I) and 8-phenyl-9-aza-7-oxabicyclo[4.2.1]nona-2,4-diene (II). The reactions are complete after 1 h at 40-50°C. Apart from the corresponding anilino alcohols, the products lack the oxygen atom of the {A figure is presented} bond. The stereochemistry of the products is indicative of an intramolecular process. Mechanistic proposals are based on an initial oxidative insertion of iron into the {A figure is presented} bond, followed by several competing reactions.
AB - A study of the reactions of Fe2(CO)9 towards the {A figure is presented} bond has extended 9-phenyl-9-aza-8-oxabicyclo[3.2.2.]nona-6-ene (I) and 8-phenyl-9-aza-7-oxabicyclo[4.2.1]nona-2,4-diene (II). The reactions are complete after 1 h at 40-50°C. Apart from the corresponding anilino alcohols, the products lack the oxygen atom of the {A figure is presented} bond. The stereochemistry of the products is indicative of an intramolecular process. Mechanistic proposals are based on an initial oxidative insertion of iron into the {A figure is presented} bond, followed by several competing reactions.
UR - https://www.scopus.com/pages/publications/28244440571
U2 - 10.1016/S0022-328X(00)90422-4
DO - 10.1016/S0022-328X(00)90422-4
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AN - SCOPUS:28244440571
SN - 0022-328X
VL - 155
SP - 63
EP - 75
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1
ER -