Reaction of superoxide anion radical [O2-] with cyclohex-2-en-1-ones

Aryeh A. Frimer; Pessia Gilinsky

doi:10.1016/S0040-4039(01)86580-1

Reaction of superoxide anion radical [O₂^-] with cyclohex-2-en-1-ones

Aryeh A. Frimer
, Pessia Gilinsky

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Cyclohex-2-en-1-ones with available acidic hydrogens undrgo base catalyzed autoxidation in the presence of KO₂/18-crown-6 in benzene yielding 2-hydroxycyclohexa-2,5-dien-1-ones in the case of 4,4- and 5,5-disubstituted substrates and 2,3-epoxycyclohexanones in the case of 6,6-disubstituted analogs; 4,4,6,6-tetrasubstituted cyclohexenones are totally inert.

Original language	English
Pages (from-to)	4331-4334
Number of pages	4
Journal	Tetrahedron Letters
Volume	20
Issue number	44
DOIs	https://doi.org/10.1016/S0040-4039(01)86580-1
State	Published - 1979

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title = "Reaction of superoxide anion radical [O2-] with cyclohex-2-en-1-ones",

abstract = "Cyclohex-2-en-1-ones with available acidic hydrogens undrgo base catalyzed autoxidation in the presence of KO2/18-crown-6 in benzene yielding 2-hydroxycyclohexa-2,5-dien-1-ones in the case of 4,4- and 5,5-disubstituted substrates and 2,3-epoxycyclohexanones in the case of 6,6-disubstituted analogs; 4,4,6,6-tetrasubstituted cyclohexenones are totally inert.",

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year = "1979",

doi = "10.1016/S0040-4039(01)86580-1",

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journal = "Tetrahedron Letters",

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AU - Frimer, Aryeh A.

AU - Gilinsky, Pessia

PY - 1979

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N2 - Cyclohex-2-en-1-ones with available acidic hydrogens undrgo base catalyzed autoxidation in the presence of KO2/18-crown-6 in benzene yielding 2-hydroxycyclohexa-2,5-dien-1-ones in the case of 4,4- and 5,5-disubstituted substrates and 2,3-epoxycyclohexanones in the case of 6,6-disubstituted analogs; 4,4,6,6-tetrasubstituted cyclohexenones are totally inert.

AB - Cyclohex-2-en-1-ones with available acidic hydrogens undrgo base catalyzed autoxidation in the presence of KO2/18-crown-6 in benzene yielding 2-hydroxycyclohexa-2,5-dien-1-ones in the case of 4,4- and 5,5-disubstituted substrates and 2,3-epoxycyclohexanones in the case of 6,6-disubstituted analogs; 4,4,6,6-tetrasubstituted cyclohexenones are totally inert.

UR - https://www.scopus.com/pages/publications/0342588973

U2 - 10.1016/S0040-4039(01)86580-1

DO - 10.1016/S0040-4039(01)86580-1

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AN - SCOPUS:0342588973

SN - 0040-4039

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EP - 4334

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 44

ER -

Reaction of superoxide anion radical [O₂^-] with cyclohex-2-en-1-ones

Abstract

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