TY - JOUR
T1 - Reaction of superoxide anion radical [O2-] with cyclohex-2-en-1-ones
AU - Frimer, Aryeh A.
AU - Gilinsky, Pessia
PY - 1979
Y1 - 1979
N2 - Cyclohex-2-en-1-ones with available acidic hydrogens undrgo base catalyzed autoxidation in the presence of KO2/18-crown-6 in benzene yielding 2-hydroxycyclohexa-2,5-dien-1-ones in the case of 4,4- and 5,5-disubstituted substrates and 2,3-epoxycyclohexanones in the case of 6,6-disubstituted analogs; 4,4,6,6-tetrasubstituted cyclohexenones are totally inert.
AB - Cyclohex-2-en-1-ones with available acidic hydrogens undrgo base catalyzed autoxidation in the presence of KO2/18-crown-6 in benzene yielding 2-hydroxycyclohexa-2,5-dien-1-ones in the case of 4,4- and 5,5-disubstituted substrates and 2,3-epoxycyclohexanones in the case of 6,6-disubstituted analogs; 4,4,6,6-tetrasubstituted cyclohexenones are totally inert.
UR - http://www.scopus.com/inward/record.url?scp=0342588973&partnerID=8YFLogxK
U2 - 10.1016/S0040-4039(01)86580-1
DO - 10.1016/S0040-4039(01)86580-1
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AN - SCOPUS:0342588973
SN - 0040-4039
VL - 20
SP - 4331
EP - 4334
JO - Tetrahedron Letters
JF - Tetrahedron Letters
IS - 44
ER -