Abstract
The reaction between 3-methoxy-4-azatricyclo-[3,3,2,02,8]deca-3, 6,9-triene and Fe2(CO)9 gives a novel σ-π-allyl heterocyclic tricarbonyliron complex (III) and methoxycarbonylcyclo- octatetraenetricarbonyliron complex (IV).
| Original language | English |
|---|---|
| Pages (from-to) | 1156 |
| Number of pages | 1 |
| Journal | Chemical Communications |
| Volume | 0 |
| Issue number | 20 |
| DOIs | |
| State | Published - 1972 |
| Externally published | Yes |
Bibliographical note
Funding Information:results. This is in agreement with the fact that (11)was described by Paquette6 as the most stable structure of the azabullvalene under consideration. It is also noteworthy that unlike the complex (I) resulting from bullvalene, the imino double bond of (111)does not enter into a second complexation. One of us (Y.B.) thanks the National Council for Ke- search and Development for a Scholarship from the Eshkol Fund. We also thank Mrs. Weininger for n.m.r. deter- minations. (Received, 24th July 1972; Com. 1270.) t Compound (11) was obtained in a quantitative yield by methylation of 7-azabicyclo[4,2,2]deca-2,4,9-trien-8-onewith methyl fluorosulphonate. $ Mass spectral data were consistent with this formulation. 1 R. Aumann, Angew. Chem., 1971,83, 175. 2 R.Aumann, Angew. Chem., 1971,83, 176, 177; R.H.Moriarty, C. L. Yeh, and R. C. Ramey. J. Amer. Chem. SOC.,1971,93,6709; A. Eisenstadt, Tetrahedron Letters, 1972, 2005. 8 L.A. Paquette, J. R. Malpass, and T. J. Barton, J. Amer. Chem. SOL, 1969,91,4714. 4 D.Bryce and J. E. Lodge, J. Chem. SOC.,1963, 695. 6 L.A. Paquette, J. R. Malpass, G. R. Krow, and T. J. Barton, J. Amer. Chem. SOC.,1969,91,5296.
Funding
results. This is in agreement with the fact that (11)was described by Paquette6 as the most stable structure of the azabullvalene under consideration. It is also noteworthy that unlike the complex (I) resulting from bullvalene, the imino double bond of (111)does not enter into a second complexation. One of us (Y.B.) thanks the National Council for Ke- search and Development for a Scholarship from the Eshkol Fund. We also thank Mrs. Weininger for n.m.r. deter- minations. (Received, 24th July 1972; Com. 1270.) t Compound (11) was obtained in a quantitative yield by methylation of 7-azabicyclo[4,2,2]deca-2,4,9-trien-8-onewith methyl fluorosulphonate. $ Mass spectral data were consistent with this formulation. 1 R. Aumann, Angew. Chem., 1971,83, 175. 2 R.Aumann, Angew. Chem., 1971,83, 176, 177; R.H.Moriarty, C. L. Yeh, and R. C. Ramey. J. Amer. Chem. SOC.,1971,93,6709; A. Eisenstadt, Tetrahedron Letters, 1972, 2005. 8 L.A. Paquette, J. R. Malpass, and T. J. Barton, J. Amer. Chem. SOL, 1969,91,4714. 4 D.Bryce and J. E. Lodge, J. Chem. SOC.,1963, 695. 6 L.A. Paquette, J. R. Malpass, G. R. Krow, and T. J. Barton, J. Amer. Chem. SOC.,1969,91,5296.
| Funders | Funder number |
|---|---|
| Eshkol Fund | |
| National Council |