Raman study of structural stability of LiCoPO 4 cathodes in LiPF 6 containing electrolytes

R. Sharabi; E. Markevich; V. Borgel; G. Salitra; G. Gershinsky; D. Aurbach; G. Semrau; M. A. Schmidt; N. Schall; C. Stinner

doi:10.1016/j.jpowsour.2011.12.018

Raman study of structural stability of LiCoPO ₄ cathodes in LiPF ₆ containing electrolytes

R. Sharabi
, E. Markevich
, V. Borgel
, G. Salitra
, G. Gershinsky
, D. Aurbach
, G. Semrau
, M. A. Schmidt
, N. Schall
, C. Stinner

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

48 Scopus citations

Abstract

Micro-probe Raman spectroscopy investigation of LiCoPO ₄ composite electrodes performed after prolonged cycling in LiPF ₆ EC/DMC electrolyte solution revealed total structural degradation of the olivine structure of the electrodes. The electrodes cycled in the identical conditions but in the presence of the HF-scavenging glassy fiber (GF) separators retain their olivine structure unchanged. The reasons for this pronounced difference are discussed.

Original language	English
Pages (from-to)	109-114
Number of pages	6
Journal	Journal of Power Sources
Volume	203
DOIs	https://doi.org/10.1016/j.jpowsour.2011.12.018
State	Published - 1 Apr 2012

Keywords

Lithium batteries, Structural degradation
Lithium-cobalt phosphate
Olivines
Raman spectroscopy

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This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.jpowsour.2011.12.018

Cite this

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title = "Raman study of structural stability of LiCoPO 4 cathodes in LiPF 6 containing electrolytes",

abstract = "Micro-probe Raman spectroscopy investigation of LiCoPO 4 composite electrodes performed after prolonged cycling in LiPF 6 EC/DMC electrolyte solution revealed total structural degradation of the olivine structure of the electrodes. The electrodes cycled in the identical conditions but in the presence of the HF-scavenging glassy fiber (GF) separators retain their olivine structure unchanged. The reasons for this pronounced difference are discussed.",

keywords = "Lithium batteries, Structural degradation, Lithium-cobalt phosphate, Olivines, Raman spectroscopy",

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T1 - Raman study of structural stability of LiCoPO 4 cathodes in LiPF 6 containing electrolytes

AU - Sharabi, R.

AU - Markevich, E.

AU - Borgel, V.

AU - Salitra, G.

AU - Gershinsky, G.

AU - Aurbach, D.

AU - Semrau, G.

AU - Schmidt, M. A.

AU - Schall, N.

AU - Stinner, C.

PY - 2012/4/1

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N2 - Micro-probe Raman spectroscopy investigation of LiCoPO 4 composite electrodes performed after prolonged cycling in LiPF 6 EC/DMC electrolyte solution revealed total structural degradation of the olivine structure of the electrodes. The electrodes cycled in the identical conditions but in the presence of the HF-scavenging glassy fiber (GF) separators retain their olivine structure unchanged. The reasons for this pronounced difference are discussed.

AB - Micro-probe Raman spectroscopy investigation of LiCoPO 4 composite electrodes performed after prolonged cycling in LiPF 6 EC/DMC electrolyte solution revealed total structural degradation of the olivine structure of the electrodes. The electrodes cycled in the identical conditions but in the presence of the HF-scavenging glassy fiber (GF) separators retain their olivine structure unchanged. The reasons for this pronounced difference are discussed.

KW - Lithium batteries, Structural degradation

KW - Lithium-cobalt phosphate

KW - Olivines

KW - Raman spectroscopy

UR - https://www.scopus.com/pages/publications/84855924254

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