Raman study of structural stability of LiCoPO 4 cathodes in LiPF 6 containing electrolytes

R. Sharabi; E. Markevich; V. Borgel; G. Salitra; G. Gershinsky; D. Aurbach; G. Semrau; M. A. Schmidt; N. Schall; C. Stinner

doi:10.1016/j.jpowsour.2011.12.018

Raman study of structural stability of LiCoPO ₄ cathodes in LiPF ₆ containing electrolytes

R. Sharabi, E. Markevich, V. Borgel, G. Salitra, G. Gershinsky, D. Aurbach, G. Semrau, M. A. Schmidt, N. Schall, C. Stinner

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

48 Scopus citations

Abstract

Micro-probe Raman spectroscopy investigation of LiCoPO ₄ composite electrodes performed after prolonged cycling in LiPF ₆ EC/DMC electrolyte solution revealed total structural degradation of the olivine structure of the electrodes. The electrodes cycled in the identical conditions but in the presence of the HF-scavenging glassy fiber (GF) separators retain their olivine structure unchanged. The reasons for this pronounced difference are discussed.

Original language	English
Pages (from-to)	109-114
Number of pages	6
Journal	Journal of Power Sources
Volume	203
DOIs	https://doi.org/10.1016/j.jpowsour.2011.12.018
State	Published - 1 Apr 2012

Keywords

Lithium batteries, Structural degradation
Lithium-cobalt phosphate
Olivines
Raman spectroscopy

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.jpowsour.2011.12.018

Cite this

@article{7f241b8ffda04efcaf9df376a5ace2cc,

title = "Raman study of structural stability of LiCoPO 4 cathodes in LiPF 6 containing electrolytes",

abstract = "Micro-probe Raman spectroscopy investigation of LiCoPO 4 composite electrodes performed after prolonged cycling in LiPF 6 EC/DMC electrolyte solution revealed total structural degradation of the olivine structure of the electrodes. The electrodes cycled in the identical conditions but in the presence of the HF-scavenging glassy fiber (GF) separators retain their olivine structure unchanged. The reasons for this pronounced difference are discussed.",

keywords = "Lithium batteries, Structural degradation, Lithium-cobalt phosphate, Olivines, Raman spectroscopy",

author = "R. Sharabi and E. Markevich and V. Borgel and G. Salitra and G. Gershinsky and D. Aurbach and G. Semrau and Schmidt, {M. A.} and N. Schall and C. Stinner",

year = "2012",

month = apr,

day = "1",

doi = "10.1016/j.jpowsour.2011.12.018",

language = "אנגלית",

volume = "203",

pages = "109--114",

journal = "Journal of Power Sources",

issn = "0378-7753",

publisher = "Elsevier",

}

TY - JOUR

T1 - Raman study of structural stability of LiCoPO 4 cathodes in LiPF 6 containing electrolytes

AU - Sharabi, R.

AU - Markevich, E.

AU - Borgel, V.

AU - Salitra, G.

AU - Gershinsky, G.

AU - Aurbach, D.

AU - Semrau, G.

AU - Schmidt, M. A.

AU - Schall, N.

AU - Stinner, C.

PY - 2012/4/1

Y1 - 2012/4/1

N2 - Micro-probe Raman spectroscopy investigation of LiCoPO 4 composite electrodes performed after prolonged cycling in LiPF 6 EC/DMC electrolyte solution revealed total structural degradation of the olivine structure of the electrodes. The electrodes cycled in the identical conditions but in the presence of the HF-scavenging glassy fiber (GF) separators retain their olivine structure unchanged. The reasons for this pronounced difference are discussed.

AB - Micro-probe Raman spectroscopy investigation of LiCoPO 4 composite electrodes performed after prolonged cycling in LiPF 6 EC/DMC electrolyte solution revealed total structural degradation of the olivine structure of the electrodes. The electrodes cycled in the identical conditions but in the presence of the HF-scavenging glassy fiber (GF) separators retain their olivine structure unchanged. The reasons for this pronounced difference are discussed.

KW - Lithium batteries, Structural degradation

KW - Lithium-cobalt phosphate

KW - Olivines

KW - Raman spectroscopy

UR - http://www.scopus.com/inward/record.url?scp=84855924254&partnerID=8YFLogxK

U2 - 10.1016/j.jpowsour.2011.12.018

DO - 10.1016/j.jpowsour.2011.12.018

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

SN - 0378-7753

VL - 203

SP - 109

EP - 114

JO - Journal of Power Sources

JF - Journal of Power Sources

ER -