TY - JOUR
T1 - Quantum heat engines and refrigerators
T2 - Continuous devices
AU - Kosloff, Ronnie
AU - Levy, Amikam
PY - 2014
Y1 - 2014
N2 - Quantum thermodynamics supplies a consistent description of quantum heat engines and refrigerators up to a single few-level system coupled to the environment. Once the environment is split into three (a hot, cold, and work reservoir), a heat engine can operate. The device converts the positive gain into power, with the gain obtained from population inversion between the components of the device. Reversing the operation transforms the device into a quantum refrigerator. The quantum tricycle, a device connected by three external leads to three heat reservoirs, is used as a template for engines and refrigerators. The equation of motion for the heat currents and power can be derived from first principles. Only a global description of the coupling of the device to the reservoirs is consistent with the first and second laws of thermodynamics. Optimization of the devices leads to a balanced set of parameters in which the couplings to the three reservoirs are of the same order and the external driving field is in resonance. When analyzing refrigerators, one needs to devote special attention to a dynamical version of the third law of thermodynamics. Bounds on the rate of cooling when Tc→0 are obtained by optimizing the cooling current. All refrigerators as Tc→0 show universal behavior. The dynamical version of the third law imposes restrictions on the scaling as Tc→0 of the relaxation rate 'gamma'c and heat capacity cV of the cold bath.
AB - Quantum thermodynamics supplies a consistent description of quantum heat engines and refrigerators up to a single few-level system coupled to the environment. Once the environment is split into three (a hot, cold, and work reservoir), a heat engine can operate. The device converts the positive gain into power, with the gain obtained from population inversion between the components of the device. Reversing the operation transforms the device into a quantum refrigerator. The quantum tricycle, a device connected by three external leads to three heat reservoirs, is used as a template for engines and refrigerators. The equation of motion for the heat currents and power can be derived from first principles. Only a global description of the coupling of the device to the reservoirs is consistent with the first and second laws of thermodynamics. Optimization of the devices leads to a balanced set of parameters in which the couplings to the three reservoirs are of the same order and the external driving field is in resonance. When analyzing refrigerators, one needs to devote special attention to a dynamical version of the third law of thermodynamics. Bounds on the rate of cooling when Tc→0 are obtained by optimizing the cooling current. All refrigerators as Tc→0 show universal behavior. The dynamical version of the third law imposes restrictions on the scaling as Tc→0 of the relaxation rate 'gamma'c and heat capacity cV of the cold bath.
KW - absolute zero temperature
KW - laser cooling
KW - quantum amplifier
KW - quantum thermodynamics
KW - quantum tricycle
UR - http://www.scopus.com/inward/record.url?scp=84897538460&partnerID=8YFLogxK
U2 - 10.1146/annurev-physchem-040513-103724
DO - 10.1146/annurev-physchem-040513-103724
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C2 - 24689798
AN - SCOPUS:84897538460
SN - 0066-426X
VL - 65
SP - 365
EP - 393
JO - Annual Review of Physical Chemistry
JF - Annual Review of Physical Chemistry
ER -