Pseudo-geminally-substituted [2.2]paracyclophanes as spacers for bisallenyl sulfoxides and sulfones

M. Lucian Birsa; Peter G. Jones; Samuel Braverman; Henning Hopf

doi:10.1055/s-2005-863715

Pseudo-geminally-substituted [2.2]paracyclophanes as spacers for bisallenyl sulfoxides and sulfones

M. Lucian Birsa
, Peter G. Jones
, Samuel Braverman
, Henning Hopf

Department of Chemistry

Technical University of Braunschweig

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The first pseudo-geminally-substituted bisallenic [2.2]paracyclophane system has been synthesized by the [2,3]sigmatropic rearrangement of propargylic sulfenates to the corresponding allenyl sulfoxides.

Original language	English
Pages (from-to)	640-642
Number of pages	3
Journal	Synlett
Issue number	4
DOIs	https://doi.org/10.1055/s-2005-863715
State	Published - 4 Mar 2005

Keywords

Allenes
Sigmatropic rearrangements
Sulfenates
Sulfones
[2.2]paracyclophanes

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10.1055/s-2005-863715

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title = "Pseudo-geminally-substituted [2.2]paracyclophanes as spacers for bisallenyl sulfoxides and sulfones",

abstract = "The first pseudo-geminally-substituted bisallenic [2.2]paracyclophane system has been synthesized by the [2,3]sigmatropic rearrangement of propargylic sulfenates to the corresponding allenyl sulfoxides.",

keywords = "Allenes, Sigmatropic rearrangements, Sulfenates, Sulfones, [2.2]paracyclophanes",

author = "\{Lucian Birsa\}, M. and Jones, \{Peter G.\} and Samuel Braverman and Henning Hopf",

year = "2005",

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doi = "10.1055/s-2005-863715",

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AU - Lucian Birsa, M.

AU - Jones, Peter G.

AU - Braverman, Samuel

AU - Hopf, Henning

PY - 2005/3/4

Y1 - 2005/3/4

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AB - The first pseudo-geminally-substituted bisallenic [2.2]paracyclophane system has been synthesized by the [2,3]sigmatropic rearrangement of propargylic sulfenates to the corresponding allenyl sulfoxides.

KW - Allenes

KW - Sigmatropic rearrangements

KW - Sulfenates

KW - Sulfones

KW - [2.2]paracyclophanes

UR - https://www.scopus.com/pages/publications/15544362423

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Pseudo-geminally-substituted [2.2]paracyclophanes as spacers for bisallenyl sulfoxides and sulfones

Abstract

Keywords

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