Probing the barrier for internal rotation of the retinal chromophore

Yoni Toker; Annette Svendsen; Anastasia V. Bochenkova; Lars H. Andersen

doi:10.1002/anie.201203746

Probing the barrier for internal rotation of the retinal chromophore

Yoni Toker, Annette Svendsen, Anastasia V. Bochenkova, Lars H. Andersen

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Molecular ion calorimetry: A technique for measuring the heat capacity of an isolated gas-phase chromophore is presented and applied to the retinal protonated Schiff base (see picture). The potential use of this technique for studying barriers for internal rotations is discussed.

Original language	English
Pages (from-to)	8757-8761
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	35
DOIs	https://doi.org/10.1002/anie.201203746
State	Published - 27 Aug 2012
Externally published	Yes

Keywords

ab initio calculations
calorimetry
chromophores
conformation analysis
photochemistry

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10.1002/anie.201203746

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title = "Probing the barrier for internal rotation of the retinal chromophore",

abstract = "Molecular ion calorimetry: A technique for measuring the heat capacity of an isolated gas-phase chromophore is presented and applied to the retinal protonated Schiff base (see picture). The potential use of this technique for studying barriers for internal rotations is discussed.",

keywords = "ab initio calculations, calorimetry, chromophores, conformation analysis, photochemistry",

author = "Yoni Toker and Annette Svendsen and Bochenkova, {Anastasia V.} and Andersen, {Lars H.}",

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AU - Svendsen, Annette

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AB - Molecular ion calorimetry: A technique for measuring the heat capacity of an isolated gas-phase chromophore is presented and applied to the retinal protonated Schiff base (see picture). The potential use of this technique for studying barriers for internal rotations is discussed.

KW - ab initio calculations

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KW - chromophores

KW - conformation analysis

KW - photochemistry

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Probing the barrier for internal rotation of the retinal chromophore

Abstract

Keywords

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