Preparation of stable porous nickel and cobalt oxides using simple inorganic precursor, instead of alkoxides, by a sonochemical technique

D. N. Srivastava; V. G. Pol; O. Palchik; L. Zhang; J. C. Yu; A. Gedanken

doi:10.1016/j.ultsonch.2004.01.003

Preparation of stable porous nickel and cobalt oxides using simple inorganic precursor, instead of alkoxides, by a sonochemical technique

D. N. Srivastava, V. G. Pol, O. Palchik, L. Zhang, J. C. Yu, A. Gedanken

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

Porous nickel and cobalt oxides were prepared using NiSO ₄·6H₂O and anhydrous Co(CH₃COO) ₂, a precursor other than alkoxides and cetyltrimethylammonium bromide as organic surfactant. The sonication method has been used for such synthesis. The surfactants were removed by calcination, as well as by solvent extraction and it is extent was examined by IR spectroscopy. The trend of removal of surfactant was followed by TGA studies and the change in phases by DSC. The products were identified by XRD. Peak in low angle XRD indicates the porous nature of the oxides. The morphology of the pores was studied by transmission electron microscopy. The pores were found less ordered, having an average size of 4-6 nm. The Brunauer-Emmet-Teller surface areas of the as-prepared, as well as the treated samples are reported having H2 and H4 type hysteresis for Ni and Co, respectively.

Original language	English
Pages (from-to)	205-212
Number of pages	8
Journal	Ultrasonics Sonochemistry
Volume	12
Issue number	3
DOIs	https://doi.org/10.1016/j.ultsonch.2004.01.003
State	Published - Feb 2005

Bibliographical note

Funding Information:
D.N.S. is thankful to the Council of Higher Education of Israel, Jerusalem for providing financial support in the form of a Post Doctoral Fellowship. A. Gedanken thanks the BMBF Germany for a DIP (Deutsche-Israeli Project) grant supporting this research.

Funding

D.N.S. is thankful to the Council of Higher Education of Israel, Jerusalem for providing financial support in the form of a Post Doctoral Fellowship. A. Gedanken thanks the BMBF Germany for a DIP (Deutsche-Israeli Project) grant supporting this research.

Funders	Funder number
Deutsche-Israeli Project
Bundesministerium für Bildung und Forschung
Council for Higher Education

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10.1016/j.ultsonch.2004.01.003

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title = "Preparation of stable porous nickel and cobalt oxides using simple inorganic precursor, instead of alkoxides, by a sonochemical technique",

abstract = "Porous nickel and cobalt oxides were prepared using NiSO 4·6H2O and anhydrous Co(CH3COO) 2, a precursor other than alkoxides and cetyltrimethylammonium bromide as organic surfactant. The sonication method has been used for such synthesis. The surfactants were removed by calcination, as well as by solvent extraction and it is extent was examined by IR spectroscopy. The trend of removal of surfactant was followed by TGA studies and the change in phases by DSC. The products were identified by XRD. Peak in low angle XRD indicates the porous nature of the oxides. The morphology of the pores was studied by transmission electron microscopy. The pores were found less ordered, having an average size of 4-6 nm. The Brunauer-Emmet-Teller surface areas of the as-prepared, as well as the treated samples are reported having H2 and H4 type hysteresis for Ni and Co, respectively.",

author = "Srivastava, {D. N.} and Pol, {V. G.} and O. Palchik and L. Zhang and Yu, {J. C.} and A. Gedanken",

note = "Funding Information: D.N.S. is thankful to the Council of Higher Education of Israel, Jerusalem for providing financial support in the form of a Post Doctoral Fellowship. A. Gedanken thanks the BMBF Germany for a DIP (Deutsche-Israeli Project) grant supporting this research.",

year = "2005",

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doi = "10.1016/j.ultsonch.2004.01.003",

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AU - Pol, V. G.

AU - Palchik, O.

AU - Zhang, L.

AU - Yu, J. C.

AU - Gedanken, A.

N1 - Funding Information: D.N.S. is thankful to the Council of Higher Education of Israel, Jerusalem for providing financial support in the form of a Post Doctoral Fellowship. A. Gedanken thanks the BMBF Germany for a DIP (Deutsche-Israeli Project) grant supporting this research.

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N2 - Porous nickel and cobalt oxides were prepared using NiSO 4·6H2O and anhydrous Co(CH3COO) 2, a precursor other than alkoxides and cetyltrimethylammonium bromide as organic surfactant. The sonication method has been used for such synthesis. The surfactants were removed by calcination, as well as by solvent extraction and it is extent was examined by IR spectroscopy. The trend of removal of surfactant was followed by TGA studies and the change in phases by DSC. The products were identified by XRD. Peak in low angle XRD indicates the porous nature of the oxides. The morphology of the pores was studied by transmission electron microscopy. The pores were found less ordered, having an average size of 4-6 nm. The Brunauer-Emmet-Teller surface areas of the as-prepared, as well as the treated samples are reported having H2 and H4 type hysteresis for Ni and Co, respectively.

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Preparation of stable porous nickel and cobalt oxides using simple inorganic precursor, instead of alkoxides, by a sonochemical technique

Abstract

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