Polysubstituted 4-piperidones and 4-piperidols: Synthesis and spatial configuration

A. M. Belostotskii; A. B. Shapiro

doi:10.1007/bf00965443

Polysubstituted 4-piperidones and 4-piperidols: Synthesis and spatial configuration

A. M. Belostotskii
, A. B. Shapiro

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Triacetonamine was used to synthesize a series of highly substituted 4-piperidones and 4-piperidols. The spatial configuration of these compounds was determined. The anionoid addition to the carbonyl group of these piperidones proceeds through highly stereoselective equatorial attack. The position of the chair-chair-twist conformational equilibrium was determined for the polysubstituted 4-piperidols.

Original language	English
Pages (from-to)	421-429
Number of pages	9
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	40
Issue number	2
DOIs	https://doi.org/10.1007/bf00965443
State	Published - Feb 1991
Externally published	Yes

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title = "Polysubstituted 4-piperidones and 4-piperidols: Synthesis and spatial configuration",

abstract = "Triacetonamine was used to synthesize a series of highly substituted 4-piperidones and 4-piperidols. The spatial configuration of these compounds was determined. The anionoid addition to the carbonyl group of these piperidones proceeds through highly stereoselective equatorial attack. The position of the chair-chair-twist conformational equilibrium was determined for the polysubstituted 4-piperidols.",

author = "Belostotskii, \{A. M.\} and Shapiro, \{A. B.\}",

year = "1991",

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AU - Shapiro, A. B.

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Y1 - 1991/2

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AB - Triacetonamine was used to synthesize a series of highly substituted 4-piperidones and 4-piperidols. The spatial configuration of these compounds was determined. The anionoid addition to the carbonyl group of these piperidones proceeds through highly stereoselective equatorial attack. The position of the chair-chair-twist conformational equilibrium was determined for the polysubstituted 4-piperidols.

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JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

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Polysubstituted 4-piperidones and 4-piperidols: Synthesis and spatial configuration

Abstract

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