Polarized absorption spectra and spectroscopic parameters of Tm 3+ in the TmAl3(BO3)4 single crystal

A. V. Malakhovskiǐ; A. É Sokolov; V. L. Temerov; L. N. Bezmaternykh; A. L. Sukhachev; V. A. Seredkin; S. L. Gnatchenko; I. S. Kachur; V. G. Piryatinskaya

doi:10.1134/s1063783408070159

Polarized absorption spectra and spectroscopic parameters of Tm ³⁺ in the TmAl₃(BO₃)₄ single crystal

A. V. Malakhovskiǐ, A. É Sokolov, V. L. Temerov, L. N. Bezmaternykh, A. L. Sukhachev, V. A. Seredkin, S. L. Gnatchenko, I. S. Kachur, V. G. Piryatinskaya

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9 Scopus citations

Abstract

High-optical-quality single crystals of the TmAl₃(BO ₃)₄ compound were synthesized from a solution in the melt. The absorption spectra in the σ and π polarizations for the ³ H ₆ → ³ F ₄, ³ H ₆ → ³ H ₅, ³ H ₆ → ³ H ₄, ³ H ₆ → ³ F ₃, ³ H ₆ → ³ F ₂, ³ H ₆ → ¹ G ₄, and ³ H ₆ → ¹ D ₂ transitions in the Tm³⁺ ion were recorded at room temperature. The transition intensities were analyzed in the framework of the Judd-Ofelt theory generalized to the case of anisotropic crystals, and the following parameters of the theory were obtained: Ω₂ = 6.14 × 10^-20 cm ², Ω₄ = 3.09 × 10^-20 cm ², and Ω₆ = 2.04 × 10^-20 cm ². The lifetimes and the branching ratios were determined for all possible transitions.

Original language	English
Pages (from-to)	1287-1293
Number of pages	7
Journal	Physics of the Solid State
Volume	50
Issue number	7
DOIs	https://doi.org/10.1134/s1063783408070159
State	Published - Jul 2008
Externally published	Yes

Bibliographical note

Funding Information:
ACKNOWLEDGMENTS This study was supported by the Russian Foundation for Basic Research (project no. 07-02-00704) and the Siberian Branch of the Russian Academy of Sciences (Integration Project no. 3.7). A.L. Sukhachev acknowledges the support of the Russian Science Support Foundation.

Funding

ACKNOWLEDGMENTS This study was supported by the Russian Foundation for Basic Research (project no. 07-02-00704) and the Siberian Branch of the Russian Academy of Sciences (Integration Project no. 3.7). A.L. Sukhachev acknowledges the support of the Russian Science Support Foundation.

Funders	Funder number
Russian Science Support Foundation
Russian Foundation for Basic Research	07-02-00704
Siberian Branch, Russian Academy of Sciences	3.7

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10.1134/s1063783408070159

Cite this

@article{b1adab7327324cc4be95babd0070036b,

title = "Polarized absorption spectra and spectroscopic parameters of Tm 3+ in the TmAl3(BO3)4 single crystal",

abstract = "High-optical-quality single crystals of the TmAl3(BO 3)4 compound were synthesized from a solution in the melt. The absorption spectra in the σ and π polarizations for the 3 H 6 → 3 F 4, 3 H 6 → 3 H 5, 3 H 6 → 3 H 4, 3 H 6 → 3 F 3, 3 H 6 → 3 F 2, 3 H 6 → 1 G 4, and 3 H 6 → 1 D 2 transitions in the Tm3+ ion were recorded at room temperature. The transition intensities were analyzed in the framework of the Judd-Ofelt theory generalized to the case of anisotropic crystals, and the following parameters of the theory were obtained: Ω2 = 6.14 × 10-20 cm 2, Ω4 = 3.09 × 10-20 cm 2, and Ω6 = 2.04 × 10-20 cm 2. The lifetimes and the branching ratios were determined for all possible transitions.",

author = "Malakhovskiǐ, {A. V.} and Sokolov, {A. {\'E}} and Temerov, {V. L.} and Bezmaternykh, {L. N.} and Sukhachev, {A. L.} and Seredkin, {V. A.} and Gnatchenko, {S. L.} and Kachur, {I. S.} and Piryatinskaya, {V. G.}",

note = "Funding Information: ACKNOWLEDGMENTS This study was supported by the Russian Foundation for Basic Research (project no. 07-02-00704) and the Siberian Branch of the Russian Academy of Sciences (Integration Project no. 3.7). A.L. Sukhachev acknowledges the support of the Russian Science Support Foundation.",

year = "2008",

month = jul,

doi = "10.1134/s1063783408070159",

language = "אנגלית",

volume = "50",

pages = "1287--1293",

journal = "Physics of the Solid State",

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T1 - Polarized absorption spectra and spectroscopic parameters of Tm 3+ in the TmAl3(BO3)4 single crystal

AU - Malakhovskiǐ, A. V.

AU - Sokolov, A. É

AU - Temerov, V. L.

AU - Bezmaternykh, L. N.

AU - Sukhachev, A. L.

AU - Seredkin, V. A.

AU - Gnatchenko, S. L.

AU - Kachur, I. S.

AU - Piryatinskaya, V. G.

N1 - Funding Information: ACKNOWLEDGMENTS This study was supported by the Russian Foundation for Basic Research (project no. 07-02-00704) and the Siberian Branch of the Russian Academy of Sciences (Integration Project no. 3.7). A.L. Sukhachev acknowledges the support of the Russian Science Support Foundation.

PY - 2008/7

Y1 - 2008/7

N2 - High-optical-quality single crystals of the TmAl3(BO 3)4 compound were synthesized from a solution in the melt. The absorption spectra in the σ and π polarizations for the 3 H 6 → 3 F 4, 3 H 6 → 3 H 5, 3 H 6 → 3 H 4, 3 H 6 → 3 F 3, 3 H 6 → 3 F 2, 3 H 6 → 1 G 4, and 3 H 6 → 1 D 2 transitions in the Tm3+ ion were recorded at room temperature. The transition intensities were analyzed in the framework of the Judd-Ofelt theory generalized to the case of anisotropic crystals, and the following parameters of the theory were obtained: Ω2 = 6.14 × 10-20 cm 2, Ω4 = 3.09 × 10-20 cm 2, and Ω6 = 2.04 × 10-20 cm 2. The lifetimes and the branching ratios were determined for all possible transitions.

AB - High-optical-quality single crystals of the TmAl3(BO 3)4 compound were synthesized from a solution in the melt. The absorption spectra in the σ and π polarizations for the 3 H 6 → 3 F 4, 3 H 6 → 3 H 5, 3 H 6 → 3 H 4, 3 H 6 → 3 F 3, 3 H 6 → 3 F 2, 3 H 6 → 1 G 4, and 3 H 6 → 1 D 2 transitions in the Tm3+ ion were recorded at room temperature. The transition intensities were analyzed in the framework of the Judd-Ofelt theory generalized to the case of anisotropic crystals, and the following parameters of the theory were obtained: Ω2 = 6.14 × 10-20 cm 2, Ω4 = 3.09 × 10-20 cm 2, and Ω6 = 2.04 × 10-20 cm 2. The lifetimes and the branching ratios were determined for all possible transitions.

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