Photoelectrochemical characterization of CuGaSe2 and Cu(Ga,In)Se2 films and defect chemical implications for solar cell performance

David Cahen, Anna Kisilev, Victor Marcu, Hans W. Schock, Rommel Noufi

Research output: Contribution to journalConference articlepeer-review

9 Scopus citations

Abstract

The effective electronic parameters and the optical bandgap of CuGaSe2 and Cu(Ga,In)Se2 films were determined by using an organic liquid electrolyte to form a Schottky barrier to the films. Trends in the electronic parameters, composition, and additional information were used in a defect chemical framework to explore the effects of Ga substitution/doping on CuInSe2. Values for optical and (effective) electronic parameters for several CuGaSe2 films are reported. Photocurrent-wavelength data are also shown. In CuGaSe2 (as in CuInSe2), film stoichiometry needs to be reasonably well controlled, close to Cu/Ga = 1, according to the results.

Original languageEnglish
Pages (from-to)1437-1442
Number of pages6
JournalConference Record of the IEEE Photovoltaic Specialists Conference
Volume2
StatePublished - 1988
Externally publishedYes
EventTwentieth IEEE Photovoltaic Specialists Conference - 1988 - Las Vegas, NV, USA
Duration: 26 Sep 198830 Sep 1988

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