Photochemistry of bridged cycloheptadienones. Di-π-methane photorearrangement of 6,7-benzobicyclo[3.2.1]octadienone and related dienes

Z. Goldschmidt; U. Gutman

doi:10.1016/S0040-4020(01)97508-8

Photochemistry of bridged cycloheptadienones. Di-π-methane photorearrangement of 6,7-benzobicyclo[3.2.1]octadienone and related dienes

Z. Goldschmidt, U. Gutman

Department of Chemistry

Bar-Ilan University

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

A series of 6,7-Benzobicyclo[3.2.1]octadienes (10-13) have been prepared. Direct and sensitized irradiation of the dienes gave di-π-methane rearrangement products (14-17). Quantum yields for the direct and sensitized rearrangements were recorded and compared. Substituent effect and structure-multiplicity relationships are discussed.

Original language	English
Pages (from-to)	3327-3331
Number of pages	5
Journal	Tetrahedron
Volume	30
Issue number	18
DOIs	https://doi.org/10.1016/S0040-4020(01)97508-8
State	Published - 1974

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Photochemistry of bridged cycloheptadienones. Di-π-methane photorearrangement of 6,7-benzobicyclo[3.2.1]octadienone and related dienes

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