Photoassociation adiabatic passage of ultracold Rb atoms to form ultracold Rb2 molecules

Evgeny A. Shapiro, Moshe Shapiro, Avi Pe'er, Jun Ye

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Abstract

We theoretically explore photoassociation by adiabatic passage of two colliding cold Rb85 atoms in an atomic trap to form an ultracold Rb2 molecule. We consider the incoherent thermal nature of the scattering process in a trap and show that coherent manipulations of the atomic ensemble, such as adiabatic passage, are feasible if performed within the coherence time window dictated by the temperature, which is relatively long for cold atoms. We show that a sequence of ∼2× 107 pulses of moderate intensities, each lasting ∼750 ns, can photoassociate a large fraction of the atomic ensemble at temperature of 100 μK and density of 1011 atoms/cm3. Use of multiple pulse sequences makes it possible to populate the ground vibrational state. Employing spontaneous decay from a selected excited state, one can accumulate the molecules in a narrow distribution of vibrational states in the ground electronic potential. Alternatively, by removing the created molecules from the beam path between pulse sets, one can create a low-density ensemble of molecules in their ground rovibrational state.

Original languageEnglish
Article number013405
JournalPhysical Review A - Atomic, Molecular, and Optical Physics
Volume75
Issue number1
DOIs
StatePublished - 2007
Externally publishedYes

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