TY - JOUR
T1 - Oxidative trimerization of o-dialkoxybenzenes to hexaalkoxytriphenylenes
T2 - Molybdenum(v) chloride as a novel reagent
AU - Kumar, Sandeep
AU - Manickam, M.
PY - 1997
Y1 - 1997
N2 - Symmetrically substituted hexaalkoxytriphenylenes are obtained from o-dialkoxybenzenes by oxidative trimerization with MoCl5 in high yields; oxidative coupling of a 3,3′,4,4′-tetraalkoxybiphenyl and 1,2-dialkoxybenzenes yields unsymmetrically substituted derivatives of triphenylene and a direct coupling of a 3,3′,4,4′-tetraalkoxybiphenyl with alkoxyphenol produces the monofunctionalized triphenylenes.
AB - Symmetrically substituted hexaalkoxytriphenylenes are obtained from o-dialkoxybenzenes by oxidative trimerization with MoCl5 in high yields; oxidative coupling of a 3,3′,4,4′-tetraalkoxybiphenyl and 1,2-dialkoxybenzenes yields unsymmetrically substituted derivatives of triphenylene and a direct coupling of a 3,3′,4,4′-tetraalkoxybiphenyl with alkoxyphenol produces the monofunctionalized triphenylenes.
UR - http://www.scopus.com/inward/record.url?scp=0001492091&partnerID=8YFLogxK
U2 - 10.1039/a704130f
DO - 10.1039/a704130f
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AN - SCOPUS:0001492091
SN - 1359-7345
SP - 1615
EP - 1616
JO - Chemical Communications
JF - Chemical Communications
IS - 17
ER -