Organometallic Studies. X. Reductive Dimerization of α-Metallocenylcarbonium Ions. I

Michael Cais; A. Eisenstadt

doi:10.1021/jo01015a047

Organometallic Studies. X. Reductive Dimerization of α-Metallocenylcarbonium Ions. I

Michael Cais, A. Eisenstadt

Technion-Israel Institute of Technology

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Abstract

Solvolysis of ferrocenylcarbinols followed by reduction with zinc leads to the formation of 1,2-diferrocenyl-ethanes in yields of 60% and better. The reaction sequence is envisaged to consist of reduction by zinc of the initially formed α-ferrocenylcarbonium ion to the ferrocenylcarbinyl radical which upon coupling yields the dimer.

Original language	English
Pages (from-to)	1148-1154
Number of pages	7
Journal	Journal of Organic Chemistry
Volume	30
Issue number	4
DOIs	https://doi.org/10.1021/jo01015a047
State	Published - 1 Apr 1965
Externally published	Yes

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abstract = "Solvolysis of ferrocenylcarbinols followed by reduction with zinc leads to the formation of 1,2-diferrocenyl-ethanes in yields of 60% and better. The reaction sequence is envisaged to consist of reduction by zinc of the initially formed α-ferrocenylcarbonium ion to the ferrocenylcarbinyl radical which upon coupling yields the dimer.",

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AB - Solvolysis of ferrocenylcarbinols followed by reduction with zinc leads to the formation of 1,2-diferrocenyl-ethanes in yields of 60% and better. The reaction sequence is envisaged to consist of reduction by zinc of the initially formed α-ferrocenylcarbonium ion to the ferrocenylcarbinyl radical which upon coupling yields the dimer.

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Organometallic Studies. X. Reductive Dimerization of α-Metallocenylcarbonium Ions. I

Abstract

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