A preponderance of ultrawideband radio communication systems under current study employ the use of pulse position modulation (PPM). However, there are significant issues related to the synchronization of PPM systems in multipath. If the multipath scattering is rich i.e. the number of reflections (paths) increases without bound as the bandwidth increases, then synchronization is impaired. In particular, it is shown that a threshold-type detector will fail in synchronizing, for any possible threshold, in the limit of large bandwidth. The maximum likelihood detector can synchronize under some severely constrained scenarios which do not appear to reflect reality in light of recent propagation measurements.