Novel, electrolyte solutions comprising fully inorganic salts with high anodic stability for rechargeable magnesium batteries

Robert E. Doe; Ruoban Han; Jaehee Hwang; Andrew J. Gmitter; Ivgeni Shterenberg; Hyun Deog Yoo; Nir Pour; Doron Aurbach

doi:10.1039/c3cc47896c

Novel, electrolyte solutions comprising fully inorganic salts with high anodic stability for rechargeable magnesium batteries

Robert E. Doe, Ruoban Han, Jaehee Hwang, Andrew J. Gmitter, Ivgeni Shterenberg, Hyun Deog Yoo, Nir Pour, Doron Aurbach

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

404 Scopus citations

Abstract

Herein the first inorganic magnesium salt solution capable of highly reversible magnesium electrodeposition is presented. Synthesized by acid–base reaction of MgCl₂ and Lewis acidic compounds such as AlCl₃, this salt class demonstrates upwards of 99% Coulombic efficiency, deposition overpotential of <200 mV, and anodic stability of 3.1 V.

Original language	English
Pages (from-to)	243-245
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	2
DOIs	https://doi.org/10.1039/c3cc47896c
State	Published - 7 Jan 2014

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abstract = "Herein the first inorganic magnesium salt solution capable of highly reversible magnesium electrodeposition is presented. Synthesized by acid–base reaction of MgCl2 and Lewis acidic compounds such as AlCl3, this salt class demonstrates upwards of 99% Coulombic efficiency, deposition overpotential of <200 mV, and anodic stability of 3.1 V.",

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AU - Doe, Robert E.

AU - Han, Ruoban

AU - Hwang, Jaehee

AU - Gmitter, Andrew J.

AU - Shterenberg, Ivgeni

AU - Yoo, Hyun Deog

AU - Pour, Nir

AU - Aurbach, Doron

PY - 2014/1/7

Y1 - 2014/1/7

N2 - Herein the first inorganic magnesium salt solution capable of highly reversible magnesium electrodeposition is presented. Synthesized by acid–base reaction of MgCl2 and Lewis acidic compounds such as AlCl3, this salt class demonstrates upwards of 99% Coulombic efficiency, deposition overpotential of <200 mV, and anodic stability of 3.1 V.

AB - Herein the first inorganic magnesium salt solution capable of highly reversible magnesium electrodeposition is presented. Synthesized by acid–base reaction of MgCl2 and Lewis acidic compounds such as AlCl3, this salt class demonstrates upwards of 99% Coulombic efficiency, deposition overpotential of <200 mV, and anodic stability of 3.1 V.

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Novel, electrolyte solutions comprising fully inorganic salts with high anodic stability for rechargeable magnesium batteries

Abstract

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