TY - JOUR
T1 - Novel carboxylated pyrrole-and carbazole-based monomers. Synthesis and electro-oxidation features
AU - Govindaraji, S
AU - Nakache, P
AU - Marks, V
AU - Pomerantz, Z
AU - Zaban, A
AU - Lellouche, J. P
PY - 2006
Y1 - 2006
N2 - Carboxylated pyrrole (Pyr, a index)- and carbazole (Cbz, b index)-containing monomers 6−7a/b and 9a/b have been readily synthesized from the monobenzyl ester of L-glutamic acid and triamine 2 using Clauson−Kaas and amide coupling reactions. In contrast to Pyr-containing compounds 6−7a, and 9a, the three Cbz-containing monomers 6−7b, and 9b have been found electroactive and were successfully electropolymerized on a Pt electrode resulting in the deposition of corresponding insoluble electroconducting polyCOOH polyCbz-films poly(6−7b) and poly(9b).
AB - Carboxylated pyrrole (Pyr, a index)- and carbazole (Cbz, b index)-containing monomers 6−7a/b and 9a/b have been readily synthesized from the monobenzyl ester of L-glutamic acid and triamine 2 using Clauson−Kaas and amide coupling reactions. In contrast to Pyr-containing compounds 6−7a, and 9a, the three Cbz-containing monomers 6−7b, and 9b have been found electroactive and were successfully electropolymerized on a Pt electrode resulting in the deposition of corresponding insoluble electroconducting polyCOOH polyCbz-films poly(6−7b) and poly(9b).
UR - https://scholar.google.co.il/scholar?q=Novel+Carboxylated+Pyrrole-+and+Carbazole-Based+Monomers.+Synthesis+and+Electro-Oxidation+Features&btnG=&hl=en&as_sdt=0%2C5
M3 - Article
VL - 71
SP - 9139
EP - 9143
JO - The Journal of Organic Chemistry
JF - The Journal of Organic Chemistry
IS - 24
ER -