NMR identification of trichloromethyl sulfoxides, sulfones and their precursors

Dan Grinstein; Samuel Braverman; Hugo E. Gottlieb

doi:10.1080/10426509808036991

NMR identification of trichloromethyl sulfoxides, sulfones and their precursors

Dan Grinstein, Samuel Braverman, Hugo E. Gottlieb

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The unusual chemistry of trichloromethylsulfenates, sulfinates, sulfoxides and sulfones is briefly reviewed. ¹³C NMR chemical shifts for both Cα (the carbon directly bound to the functional group) and the CCl₃ group are reported, as a useful diagnostic tool for determining the nature of the sulfur-containing moiety.

Original language	English
Pages (from-to)	259-263
Number of pages	5
Journal	Phosphorus, Sulfur and Silicon and the Related Elements
Volume	132
DOIs	https://doi.org/10.1080/10426509808036991
State	Published - 1998

Bibliographical note

Funding Information:
We are grateful to the ISRAEL SCIENCE FOUNDATION for financial support of this study.

Keywords

NMR
Sulfenates
Sulfinates
Sulfones
Sulfoxides
Trichloromethyl group

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abstract = "The unusual chemistry of trichloromethylsulfenates, sulfinates, sulfoxides and sulfones is briefly reviewed. 13C NMR chemical shifts for both Cα (the carbon directly bound to the functional group) and the CCl3 group are reported, as a useful diagnostic tool for determining the nature of the sulfur-containing moiety.",

keywords = "NMR, Sulfenates, Sulfinates, Sulfones, Sulfoxides, Trichloromethyl group",

author = "Dan Grinstein and Samuel Braverman and Gottlieb, {Hugo E.}",

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AU - Braverman, Samuel

AU - Gottlieb, Hugo E.

N1 - Funding Information: We are grateful to the ISRAEL SCIENCE FOUNDATION for financial support of this study.

PY - 1998

Y1 - 1998

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AB - The unusual chemistry of trichloromethylsulfenates, sulfinates, sulfoxides and sulfones is briefly reviewed. 13C NMR chemical shifts for both Cα (the carbon directly bound to the functional group) and the CCl3 group are reported, as a useful diagnostic tool for determining the nature of the sulfur-containing moiety.

KW - NMR

KW - Sulfenates

KW - Sulfinates

KW - Sulfones

KW - Sulfoxides

KW - Trichloromethyl group

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ER -

NMR identification of trichloromethyl sulfoxides, sulfones and their precursors

Abstract

Bibliographical note

Keywords

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