Multi-component hybrid inorganic-organic-inorganic particles with various metal oxide outer shells

Miroslava Malenovska; Marco Litschauer; Marie Alexandra Neouze; Ulrich Schubert; Anna Peled; Jean Paul Lellouche

doi:10.1016/j.jorganchem.2008.09.035

Multi-component hybrid inorganic-organic-inorganic particles with various metal oxide outer shells

Miroslava Malenovska, Marco Litschauer, Marie Alexandra Neouze, Ulrich Schubert, Anna Peled, Jean Paul Lellouche

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Non-agglomerated hybrid particles of 200 nm diameter with an outer metal oxide shell were prepared by reacting the COOH groups of poly((S)-N-dicarbazolyl-lysine)-covered silica particles with metal alkoxides, such as titanium, zirconium and aluminum alkoxides, followed by sol-gel processing. With tetraethoxysilane (Si(OEt)₄), the silica particle core was growing rather than forming an external metal oxide shell, as observed for the other tested metal alkoxides.

Original language	English
Pages (from-to)	1076-1080
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	694
Issue number	7-8
DOIs	https://doi.org/10.1016/j.jorganchem.2008.09.035
State	Published - 1 Apr 2009

Bibliographical note

Funding Information:
This work was supported by the European Commission in the framework of the FP6 Integrated Project NAPOLYDE (Contract No. NMP2-CT-2005-515846).

Keywords

Inorganic-organic hybrid materials
Metal alkoxides
Multi-layered particles
Sol-gel processing

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10.1016/j.jorganchem.2008.09.035

Cite this

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title = "Multi-component hybrid inorganic-organic-inorganic particles with various metal oxide outer shells",

abstract = "Non-agglomerated hybrid particles of 200 nm diameter with an outer metal oxide shell were prepared by reacting the COOH groups of poly((S)-N-dicarbazolyl-lysine)-covered silica particles with metal alkoxides, such as titanium, zirconium and aluminum alkoxides, followed by sol-gel processing. With tetraethoxysilane (Si(OEt)4), the silica particle core was growing rather than forming an external metal oxide shell, as observed for the other tested metal alkoxides.",

keywords = "Inorganic-organic hybrid materials, Metal alkoxides, Multi-layered particles, Sol-gel processing",

author = "Miroslava Malenovska and Marco Litschauer and Neouze, {Marie Alexandra} and Ulrich Schubert and Anna Peled and Lellouche, {Jean Paul}",

note = "Funding Information: This work was supported by the European Commission in the framework of the FP6 Integrated Project NAPOLYDE (Contract No. NMP2-CT-2005-515846).",

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doi = "10.1016/j.jorganchem.2008.09.035",

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T1 - Multi-component hybrid inorganic-organic-inorganic particles with various metal oxide outer shells

AU - Malenovska, Miroslava

AU - Litschauer, Marco

AU - Neouze, Marie Alexandra

AU - Schubert, Ulrich

AU - Peled, Anna

AU - Lellouche, Jean Paul

N1 - Funding Information: This work was supported by the European Commission in the framework of the FP6 Integrated Project NAPOLYDE (Contract No. NMP2-CT-2005-515846).

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N2 - Non-agglomerated hybrid particles of 200 nm diameter with an outer metal oxide shell were prepared by reacting the COOH groups of poly((S)-N-dicarbazolyl-lysine)-covered silica particles with metal alkoxides, such as titanium, zirconium and aluminum alkoxides, followed by sol-gel processing. With tetraethoxysilane (Si(OEt)4), the silica particle core was growing rather than forming an external metal oxide shell, as observed for the other tested metal alkoxides.

AB - Non-agglomerated hybrid particles of 200 nm diameter with an outer metal oxide shell were prepared by reacting the COOH groups of poly((S)-N-dicarbazolyl-lysine)-covered silica particles with metal alkoxides, such as titanium, zirconium and aluminum alkoxides, followed by sol-gel processing. With tetraethoxysilane (Si(OEt)4), the silica particle core was growing rather than forming an external metal oxide shell, as observed for the other tested metal alkoxides.

KW - Inorganic-organic hybrid materials

KW - Metal alkoxides

KW - Multi-layered particles

KW - Sol-gel processing

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ER -

Multi-component hybrid inorganic-organic-inorganic particles with various metal oxide outer shells

Abstract

Bibliographical note

Keywords

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