Monomeric iron(II) hydroxo and iron(III) dihydroxo complexes stabilized by intermolecular hydrogen bonding

Laurent Bénisvy; Sabine Halut; Bruno Donnadieu; Jean Pierre Tuchagues; Jean Claude Chottard; Yun Li

doi:10.1021/ic060100r

Monomeric iron(II) hydroxo and iron(III) dihydroxo complexes stabilized by intermolecular hydrogen bonding

Laurent Bénisvy, Sabine Halut, Bruno Donnadieu, Jean Pierre Tuchagues, Jean Claude Chottard, Yun Li

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

Using the multidentate ligand bis(N-methylimidazol-2-yl)-3- methylthiopropanol (L), the mononuclear iron(II) hydroxo and iron(III) dihydroxo complexes [Fe^II(L)₂(OH)](BF₄) (1) and [Fe ^III(L)₂(OH)₂](BF₄) (2) have been synthesized and characterized by X-ray diffraction and spectroscopic methods. The X-ray data suggest that the remarkable stability of the Fe-OH bond(s) in both compounds results from intermolecular hydrogen-bonding interactions between the hydroxo ligand(s) and the tertiary hydroxyl of the L ligands, which prevent further intermolecular reactions.

Original language	English
Pages (from-to)	2403-2405
Number of pages	3
Journal	Inorganic Chemistry
Volume	45
Issue number	6
DOIs	https://doi.org/10.1021/ic060100r
State	Published - 20 Mar 2006
Externally published	Yes

Access to Document

10.1021/ic060100r

Cite this

@article{deb25fd622dd449ea14b401a04f99ae6,

title = "Monomeric iron(II) hydroxo and iron(III) dihydroxo complexes stabilized by intermolecular hydrogen bonding",

abstract = "Using the multidentate ligand bis(N-methylimidazol-2-yl)-3- methylthiopropanol (L), the mononuclear iron(II) hydroxo and iron(III) dihydroxo complexes [FeII(L)2(OH)](BF4) (1) and [Fe III(L)2(OH)2](BF4) (2) have been synthesized and characterized by X-ray diffraction and spectroscopic methods. The X-ray data suggest that the remarkable stability of the Fe-OH bond(s) in both compounds results from intermolecular hydrogen-bonding interactions between the hydroxo ligand(s) and the tertiary hydroxyl of the L ligands, which prevent further intermolecular reactions.",

author = "Laurent B{\'e}nisvy and Sabine Halut and Bruno Donnadieu and Tuchagues, {Jean Pierre} and Chottard, {Jean Claude} and Yun Li",

year = "2006",

month = mar,

day = "20",

doi = "10.1021/ic060100r",

language = "אנגלית",

volume = "45",

pages = "2403--2405",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "6",

}

TY - JOUR

T1 - Monomeric iron(II) hydroxo and iron(III) dihydroxo complexes stabilized by intermolecular hydrogen bonding

AU - Bénisvy, Laurent

AU - Halut, Sabine

AU - Donnadieu, Bruno

AU - Tuchagues, Jean Pierre

AU - Chottard, Jean Claude

AU - Li, Yun

PY - 2006/3/20

Y1 - 2006/3/20

N2 - Using the multidentate ligand bis(N-methylimidazol-2-yl)-3- methylthiopropanol (L), the mononuclear iron(II) hydroxo and iron(III) dihydroxo complexes [FeII(L)2(OH)](BF4) (1) and [Fe III(L)2(OH)2](BF4) (2) have been synthesized and characterized by X-ray diffraction and spectroscopic methods. The X-ray data suggest that the remarkable stability of the Fe-OH bond(s) in both compounds results from intermolecular hydrogen-bonding interactions between the hydroxo ligand(s) and the tertiary hydroxyl of the L ligands, which prevent further intermolecular reactions.

AB - Using the multidentate ligand bis(N-methylimidazol-2-yl)-3- methylthiopropanol (L), the mononuclear iron(II) hydroxo and iron(III) dihydroxo complexes [FeII(L)2(OH)](BF4) (1) and [Fe III(L)2(OH)2](BF4) (2) have been synthesized and characterized by X-ray diffraction and spectroscopic methods. The X-ray data suggest that the remarkable stability of the Fe-OH bond(s) in both compounds results from intermolecular hydrogen-bonding interactions between the hydroxo ligand(s) and the tertiary hydroxyl of the L ligands, which prevent further intermolecular reactions.

UR - http://www.scopus.com/inward/record.url?scp=33645523278&partnerID=8YFLogxK

U2 - 10.1021/ic060100r

DO - 10.1021/ic060100r

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

C2 - 16529458

AN - SCOPUS:33645523278

SN - 0020-1669

VL - 45

SP - 2403

EP - 2405

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 6

ER -

Monomeric iron(II) hydroxo and iron(III) dihydroxo complexes stabilized by intermolecular hydrogen bonding

Abstract

Access to Document

Other files and links

Fingerprint

Cite this