TY - JOUR
T1 - Molecular monolayer-mediated control over semiconductor surfaces
T2 - Evidence for molecular depolarization of silane monolayers on Si/SiOx
AU - Gershevitz, Olga
AU - Sukenik, Chaim N.
AU - Ghabboun, Jamal
AU - Cahen, David
PY - 2003/4/23
Y1 - 2003/4/23
N2 - We show that, for molecules with particularly strong dipoles, their organization into a monomolecular layer can lead to depolarization, something that limits the range over which the substrate's work function can be changed. It appears that, with molecules, depolarization is achieved by changes in orientation and conformation, rather than by charge transfer to the substrate as is common for atomic layers.
AB - We show that, for molecules with particularly strong dipoles, their organization into a monomolecular layer can lead to depolarization, something that limits the range over which the substrate's work function can be changed. It appears that, with molecules, depolarization is achieved by changes in orientation and conformation, rather than by charge transfer to the substrate as is common for atomic layers.
UR - http://www.scopus.com/inward/record.url?scp=0037462126&partnerID=8YFLogxK
U2 - 10.1021/ja029529h
DO - 10.1021/ja029529h
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C2 - 12696890
AN - SCOPUS:0037462126
SN - 0002-7863
VL - 125
SP - 4730
EP - 4731
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 16
ER -