Abstract
Herein we demonstrate the use of host-guest chemistry to modulate rates of charge transport in metal-organic framework (MOF) films. The kinetics of site-to-site of charge hopping and, in turn, the overall redox conductivity, of a ferrocene-modified MOF can be altered by up to 30-fold by coupling electron exchange to the oxidation-state-dependent formation of inclusion complexes between cyclodextrin and channel-tethered metallocenes.
| Original language | English |
|---|---|
| Pages (from-to) | 1705-1708 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 52 |
| Issue number | 8 |
| DOIs | |
| State | Published - 28 Jan 2016 |
| Externally published | Yes |
Bibliographical note
Publisher Copyright:© The Royal Society of Chemistry 2016.
Funding
This work was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, grant no. DE-FG02-87ER13808 and by Northwestern University.
| Funders | Funder number |
|---|---|
| U.S. Department of Energy | |
| Office of Science | |
| Basic Energy Sciences | DE-FG02-87ER13808 |
| Northwestern University |
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