TY - JOUR
T1 - Metal-free boron-doped graphene for selective electroreduction of carbon dioxide to formic acid/formate
AU - Sreekanth, Narayanaru
AU - Nazrulla, Mohammed Azeezulla
AU - Vineesh, Thazhe Veettil
AU - Sailaja, Krishnamurty
AU - Phani, Kanala Lakshminarasimha
N1 - Publisher Copyright:
© The Royal Society of Chemistry 2015.
PY - 2015
Y1 - 2015
N2 - Herein we report the electrocatalytic activity of boron-doped graphene for the reduction of CO2. Electrolysis takes place at low overpotentials leading exclusively to formate as the product (vis-à-vis benchmark Bi catalyst). Computational studies reveal mechanistic details of CO2 adsorption and subsequent conversion to formic acid/formate.
AB - Herein we report the electrocatalytic activity of boron-doped graphene for the reduction of CO2. Electrolysis takes place at low overpotentials leading exclusively to formate as the product (vis-à-vis benchmark Bi catalyst). Computational studies reveal mechanistic details of CO2 adsorption and subsequent conversion to formic acid/formate.
UR - http://www.scopus.com/inward/record.url?scp=84945946022&partnerID=8YFLogxK
U2 - 10.1039/c5cc06051f
DO - 10.1039/c5cc06051f
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AN - SCOPUS:84945946022
SN - 1359-7345
VL - 51
SP - 16061
EP - 16064
JO - Chemical Communications
JF - Chemical Communications
IS - 89
ER -