Mechanism of resistive switching in 3, 4, 9, 10 perylenetetracarboxylic dianhydride (PTCDA) sandwiched between metal electrodes

Ruchi Agrawal, Pramod Kumar, Subhasis Ghosh

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

Electrical-field-induced resistive transitions in thin films of perylenetetracarboxylic dianhydride sandwiched between two metal electrodes, from an insulating state to a conducting state with a high on-off ratio, have been studied. Temperature dependence of resistivity and scanning tunneling spectroscopic studies show insulating behavior in off state and metallic behavior in on state. Devices with a thin intermediate layer of LiF between metal electrode and organic layer, or devices fabricated in planar configuration, do not show switching behavior. All these suggest that conducting pathways are responsible for the electric-field-induced conductance transition.

Original languageEnglish
Pages (from-to)2795-2799
Number of pages5
JournalIEEE Transactions on Electron Devices
Volume55
Issue number10
DOIs
StatePublished - 2008
Externally publishedYes

Bibliographical note

Funding Information:
Manuscript received February 12, 2008; revised May 27, 2008. Current version published September 24, 2008. This work was supported in part by the Department of Science and Technology, Government of India. The work of R. Agrawal and P. Kumar was supported by UGC-CSIR through fellowship. The review of this brief was arranged by J. Kanicki.

Funding

Manuscript received February 12, 2008; revised May 27, 2008. Current version published September 24, 2008. This work was supported in part by the Department of Science and Technology, Government of India. The work of R. Agrawal and P. Kumar was supported by UGC-CSIR through fellowship. The review of this brief was arranged by J. Kanicki.

FundersFunder number
UGC-CSIR
Department of Science and Technology, Ministry of Science and Technology, India

    Keywords

    • Organic compounds
    • Perylenetetracarboxylic dianhydride (PTCDA)
    • Resistive switching

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