Mechanism of oxidation of aquated copper(II) ions by hydroxyl free radicals. A high-pressure pulse-radiolysis experiment

Haim Cohen; Rudi van Eldik; Mohamed Masarwa; Dan Meyerstein

doi:10.1016/s0020-1693(00)91905-4

Mechanism of oxidation of aquated copper(II) ions by hydroxyl free radicals. A high-pressure pulse-radiolysis experiment

Haim Cohen, Rudi van Eldik, Mohamed Masarwa, Dan Meyerstein

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The pressure dependence of the reaction Cu(H₂O)_m²⁺ + ^·OH→Cu(III)_aq+OH^-, studied using pulse-radiolysis techniques at pressures up to 150 MPa, suggests a rate-determining ligand interchange mechanism.

Original language	English
Pages (from-to)	31-34
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	177
Issue number	1
DOIs	https://doi.org/10.1016/s0020-1693(00)91905-4
State	Published - 1 Nov 1990
Externally published	Yes

Bibliographical note

Funding Information:
This study was supported in part by a grant from the Israel Atomic Energy Commission and the Planning and Granting Committee of the Council of Higher Education, Jerusalem. R.v.E. acknowledges financial support from the Deutsche Forschungs-gemeinschafta nd the Volkswagen-Stiftung. The authors gratefully acknowledges upport from the German-Israeli Foundation for Scientific Research and Development. D.M. wishes to expressh is thanks to Mrs Irene Evans for her continued interest and support.

Funding

This study was supported in part by a grant from the Israel Atomic Energy Commission and the Planning and Granting Committee of the Council of Higher Education, Jerusalem. R.v.E. acknowledges financial support from the Deutsche Forschungs-gemeinschafta nd the Volkswagen-Stiftung. The authors gratefully acknowledges upport from the German-Israeli Foundation for Scientific Research and Development. D.M. wishes to expressh is thanks to Mrs Irene Evans for her continued interest and support.

Funders	Funder number
Deutsche Forschungs-gemeinschafta
Volkswagen Foundation
German-Israeli Foundation for Scientific Research and Development
Israel Atomic Energy Commission

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10.1016/s0020-1693(00)91905-4

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title = "Mechanism of oxidation of aquated copper(II) ions by hydroxyl free radicals. A high-pressure pulse-radiolysis experiment",

abstract = "The pressure dependence of the reaction Cu(H2O)m2+ + ·OH→Cu(III)aq+OH-, studied using pulse-radiolysis techniques at pressures up to 150 MPa, suggests a rate-determining ligand interchange mechanism.",

author = "Haim Cohen and {van Eldik}, Rudi and Mohamed Masarwa and Dan Meyerstein",

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AU - Meyerstein, Dan

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Mechanism of oxidation of aquated copper(II) ions by hydroxyl free radicals. A high-pressure pulse-radiolysis experiment

Abstract

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Funding

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