The pressure dependence of the reaction Cu(H2O)m2+ + ·OH→Cu(III)aq+OH-, studied using pulse-radiolysis techniques at pressures up to 150 MPa, suggests a rate-determining ligand interchange mechanism.
|Number of pages||4|
|Journal||Inorganica Chimica Acta|
|State||Published - 1 Nov 1990|
Bibliographical noteFunding Information:
This study was supported in part by a grant from the Israel Atomic Energy Commission and the Planning and Granting Committee of the Council of Higher Education, Jerusalem. R.v.E. acknowledges financial support from the Deutsche Forschungs-gemeinschafta nd the Volkswagen-Stiftung. The authors gratefully acknowledges upport from the German-Israeli Foundation for Scientific Research and Development. D.M. wishes to expressh is thanks to Mrs Irene Evans for her continued interest and support.