Mechanism of oxidation of aquated copper(II) ions by hydroxyl free radicals. A high-pressure pulse-radiolysis experiment

Haim Cohen; Rudi van Eldik; Mohamed Masarwa; Dan Meyerstein

doi:10.1016/S0020-1693(00)91905-4

Mechanism of oxidation of aquated copper(II) ions by hydroxyl free radicals. A high-pressure pulse-radiolysis experiment

Haim Cohen, Rudi van Eldik, Mohamed Masarwa, Dan Meyerstein

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

The pressure dependence of the reaction Cu(H₂O)_m²⁺ + ^·OH→Cu(III)_aq+OH^-, studied using pulse-radiolysis techniques at pressures up to 150 MPa, suggests a rate-determining ligand interchange mechanism.

Original language	English
Pages (from-to)	31-34
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	177
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(00)91905-4
State	Published - 1 Nov 1990
Externally published	Yes

Bibliographical note

Funding Information:
This study was supported in part by a grant from the Israel Atomic Energy Commission and the Planning and Granting Committee of the Council of Higher Education, Jerusalem. R.v.E. acknowledges financial support from the Deutsche Forschungs-gemeinschafta nd the Volkswagen-Stiftung. The authors gratefully acknowledges upport from the German-Israeli Foundation for Scientific Research and Development. D.M. wishes to expressh is thanks to Mrs Irene Evans for her continued interest and support.

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title = "Mechanism of oxidation of aquated copper(II) ions by hydroxyl free radicals. A high-pressure pulse-radiolysis experiment",

abstract = "The pressure dependence of the reaction Cu(H2O)m2+ + ·OH→Cu(III)aq+OH-, studied using pulse-radiolysis techniques at pressures up to 150 MPa, suggests a rate-determining ligand interchange mechanism.",

author = "Haim Cohen and {van Eldik}, Rudi and Mohamed Masarwa and Dan Meyerstein",

note = "Funding Information: This study was supported in part by a grant from the Israel Atomic Energy Commission and the Planning and Granting Committee of the Council of Higher Education, Jerusalem. R.v.E. acknowledges financial support from the Deutsche Forschungs-gemeinschafta nd the Volkswagen-Stiftung. The authors gratefully acknowledges upport from the German-Israeli Foundation for Scientific Research and Development. D.M. wishes to expressh is thanks to Mrs Irene Evans for her continued interest and support.",

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AU - Masarwa, Mohamed

AU - Meyerstein, Dan

N1 - Funding Information: This study was supported in part by a grant from the Israel Atomic Energy Commission and the Planning and Granting Committee of the Council of Higher Education, Jerusalem. R.v.E. acknowledges financial support from the Deutsche Forschungs-gemeinschafta nd the Volkswagen-Stiftung. The authors gratefully acknowledges upport from the German-Israeli Foundation for Scientific Research and Development. D.M. wishes to expressh is thanks to Mrs Irene Evans for her continued interest and support.

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Mechanism of oxidation of aquated copper(II) ions by hydroxyl free radicals. A high-pressure pulse-radiolysis experiment

Abstract

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