Mass spectrometric study of some organotellurium(IV) compounds

Miriam Cojocaru, Iris Elyashiv, Michael Albeck

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6 Scopus citations

Abstract

A series of tetracoordinated organotellurium(IV) compounds with potential immunomodulating properties were studied mass spectrometrically using high-resolution positive ion desorption chemical ionization and constant B/E and B2/E linked-scanning techniques. The nature of the organic ligand bonded to the Te(IV) has a major influence on the mass spectral behavior of these compounds. When only monodentate ligands -OR are bonded to the Te(IV), no molecular or protonated molecular ion appears in the spectrum, although polynuclear species are present. When the compounds contain bis-bidentate ligands of the type -ORO-, the protonated molecular ion becomes the base peak and the polynuclear species are not present.

Original languageEnglish
Pages (from-to)705-713
Number of pages9
JournalJournal of Mass Spectrometry
Volume32
Issue number7
DOIs
StatePublished - Jul 1997

Keywords

  • High-resolution positive ion desorption chemical ionization
  • Monomers
  • Polymers
  • Tandem mass spectrometric
  • Tetracoordinated organotellurium(IV) compounds

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