Abstract
Troponeiron tricarbonyl and 7-methyltroponeiron tricarbonyl undergo kinetically controlled oxygen protonation at low temperatures to give the corresponding hydroxytropyliumiron tricarbonyl cations, observable by 1C and 1H NMR spectroscopy. At higher temperatures, the oxygen-protonated species isomerize to yield the thermodynamically more stable carbon-protonated pentadienyliron tricarbonyl cations.
Original language | English |
---|---|
Pages (from-to) | C14-C18 |
Journal | Journal of Organometallic Chemistry |
Volume | 127 |
Issue number | 1 |
DOIs | |
State | Published - 22 Feb 1977 |
Externally published | Yes |
Bibliographical note
Funding Information:Acknowledgment is made to the Donors of the Petroleum Research Fund, administered by the American Chemical Society, for support of this research.
Funding
Acknowledgment is made to the Donors of the Petroleum Research Fund, administered by the American Chemical Society, for support of this research.
Funders | Funder number |
---|---|
American Chemical Society |