Low-Cost and Scalable Ni-Prussian Blue Analogue//Functionalized Carbon Based Na-Ion Systems for all Climate Operations

Pappu Naskar; Subhrajyoti Debnath; Apurba Maiti; Biplab Biswas; Anjan Banerjee

doi:10.1002/cphc.202200588

Low-Cost and Scalable Ni-Prussian Blue Analogue//Functionalized Carbon Based Na-Ion Systems for all Climate Operations

Pappu Naskar
, Subhrajyoti Debnath
, Apurba Maiti
, Biplab Biswas
, Anjan Banerjee

Presidency College India

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Herein, we have developed a sodium ion based aqueous energy storage device with nickel prussian-blue-analogue (Ni-PBA) positive and functionalized carbon-black negative electrodes in 1 M Na₂SO₄ electrolyte solution. The components required to develop the device, i. e., stainless steel (SS) current-collectors, absorbent-glass-mat separator, electrolyte, carbon-black, and precursors of Ni-PBA, are all environmentally benign and inexpensive. To minimize the corrosion of pristine-SS, polyaniline coating on the SS surface is applied by in situ electrodeposition method. The full cell exhibits a specific capacity of 28 mAh g⁻¹ with 90 % Coulomb efficiency (@0.2C), an energy density of 34 Wh kg⁻¹ (@20 W kg⁻¹), a power density of 100 W kg⁻¹ (@18 Wh kg⁻¹) and a good life cycle (70 % capacity-retention over 500 cycles @1.0C rate) within the 0–1.2 V window. The cell performance is further tested under variable temperatures, and 0–50 °C range is reported to be the working window for this cell.

Original language	English
Article number	e202200588
Journal	ChemPhysChem
Volume	24
Issue number	4
Early online date	4 Oct 2022
DOIs	https://doi.org/10.1002/cphc.202200588
State	Published - 14 Feb 2023
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2022 Wiley-VCH GmbH.

Funding

Financial support from Science and Engineering Research Board (SERB), India (File No: SRG/2019/000296) and University Grants Commission (UGC), India (No. F.30‐509/(BSR)) are gratefully acknowledged. PN, SD and AM thank to Council of Scientific and Industrial Research (CSIR), India for SRF (File No: 08/155(0064)/2019‐EMR‐1), JRF (File No: 08/0155(12174)/2021‐EMR‐1), and JRF (File No: 08/0155(13430)/2022‐EMR‐1), respectively.

Funders	Funder number
Joseph Rowntree Foundation	08/0155(13430)/2022‐EMR‐1, 08/0155(12174)/2021‐EMR‐1
Council of Scientific and Industrial Research, India	08/155(0064)/2019‐EMR‐1
University Grants Commission	.30‐509/(BSR)
Science and Engineering Research Board	SRG/2019/000296

Keywords

carbon
energy conversion
prussian blue analogue
sodium-ion battery
stainless steel corrosion

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1002/cphc.202200588

Cite this

@article{6dd3291dd64f4462ad6b4912b6f2a423,

title = "Low-Cost and Scalable Ni-Prussian Blue Analogue//Functionalized Carbon Based Na-Ion Systems for all Climate Operations",

abstract = "Herein, we have developed a sodium ion based aqueous energy storage device with nickel prussian-blue-analogue (Ni-PBA) positive and functionalized carbon-black negative electrodes in 1 M Na2SO4 electrolyte solution. The components required to develop the device, i. e., stainless steel (SS) current-collectors, absorbent-glass-mat separator, electrolyte, carbon-black, and precursors of Ni-PBA, are all environmentally benign and inexpensive. To minimize the corrosion of pristine-SS, polyaniline coating on the SS surface is applied by in situ electrodeposition method. The full cell exhibits a specific capacity of 28 mAh g−1 with 90 \% Coulomb efficiency (@0.2C), an energy density of 34 Wh kg−1 (@20 W kg−1), a power density of 100 W kg−1 (@18 Wh kg−1) and a good life cycle (70 \% capacity-retention over 500 cycles @1.0C rate) within the 0–1.2 V window. The cell performance is further tested under variable temperatures, and 0–50 °C range is reported to be the working window for this cell.",

keywords = "carbon, energy conversion, prussian blue analogue, sodium-ion battery, stainless steel corrosion",

author = "Pappu Naskar and Subhrajyoti Debnath and Apurba Maiti and Biplab Biswas and Anjan Banerjee",

note = "Publisher Copyright: {\textcopyright} 2022 Wiley-VCH GmbH.",

year = "2023",

month = feb,

day = "14",

doi = "10.1002/cphc.202200588",

language = "אנגלית",

volume = "24",

journal = "ChemPhysChem",

issn = "1439-4235",

publisher = "Wiley-VCH Verlag",

number = "4",

}

TY - JOUR

T1 - Low-Cost and Scalable Ni-Prussian Blue Analogue//Functionalized Carbon Based Na-Ion Systems for all Climate Operations

AU - Naskar, Pappu

AU - Debnath, Subhrajyoti

AU - Maiti, Apurba

AU - Biswas, Biplab

AU - Banerjee, Anjan

PY - 2023/2/14

Y1 - 2023/2/14

N2 - Herein, we have developed a sodium ion based aqueous energy storage device with nickel prussian-blue-analogue (Ni-PBA) positive and functionalized carbon-black negative electrodes in 1 M Na2SO4 electrolyte solution. The components required to develop the device, i. e., stainless steel (SS) current-collectors, absorbent-glass-mat separator, electrolyte, carbon-black, and precursors of Ni-PBA, are all environmentally benign and inexpensive. To minimize the corrosion of pristine-SS, polyaniline coating on the SS surface is applied by in situ electrodeposition method. The full cell exhibits a specific capacity of 28 mAh g−1 with 90 % Coulomb efficiency (@0.2C), an energy density of 34 Wh kg−1 (@20 W kg−1), a power density of 100 W kg−1 (@18 Wh kg−1) and a good life cycle (70 % capacity-retention over 500 cycles @1.0C rate) within the 0–1.2 V window. The cell performance is further tested under variable temperatures, and 0–50 °C range is reported to be the working window for this cell.

AB - Herein, we have developed a sodium ion based aqueous energy storage device with nickel prussian-blue-analogue (Ni-PBA) positive and functionalized carbon-black negative electrodes in 1 M Na2SO4 electrolyte solution. The components required to develop the device, i. e., stainless steel (SS) current-collectors, absorbent-glass-mat separator, electrolyte, carbon-black, and precursors of Ni-PBA, are all environmentally benign and inexpensive. To minimize the corrosion of pristine-SS, polyaniline coating on the SS surface is applied by in situ electrodeposition method. The full cell exhibits a specific capacity of 28 mAh g−1 with 90 % Coulomb efficiency (@0.2C), an energy density of 34 Wh kg−1 (@20 W kg−1), a power density of 100 W kg−1 (@18 Wh kg−1) and a good life cycle (70 % capacity-retention over 500 cycles @1.0C rate) within the 0–1.2 V window. The cell performance is further tested under variable temperatures, and 0–50 °C range is reported to be the working window for this cell.

KW - carbon

KW - energy conversion

KW - prussian blue analogue

KW - sodium-ion battery

KW - stainless steel corrosion

UR - https://www.scopus.com/pages/publications/85142352003

U2 - 10.1002/cphc.202200588

DO - 10.1002/cphc.202200588

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

C2 - 36196021

AN - SCOPUS:85142352003

SN - 1439-4235

VL - 24

JO - ChemPhysChem

JF - ChemPhysChem

IS - 4

M1 - e202200588

ER -

Low-Cost and Scalable Ni-Prussian Blue Analogue//Functionalized Carbon Based Na-Ion Systems for all Climate Operations

Abstract

Bibliographical note

Funding

Keywords

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this