Isotope effects on franck-condon factors. V. Electronic transitions of isotopic O2, N2, C2, and H2 molecules

M. Halmann, I. Laulicht

Research output: Contribution to journalArticlepeer-review

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Abstract

Arrays of Franck-Condon factors for vibrational quantum numbers up to v′ and v″ =14 were computed using Morse potentials, for the Schumann-Runge bands of 16O2, 16O 18O, and 18O2, for the first positive and the Vegard-Kaplan band systems of 14N2 and 14N 15N, for the Swan bands of 12C2 and 12C13C, and for the Lyman bands of H2 and D2. The isotope effects on vibrational transition probabilities are large at the minima between the loci of the Franck-Condon parabolas and smallest at the loci of the maxima.

Original languageEnglish
Pages (from-to)2398-2405
Number of pages8
JournalJournal of Chemical Physics
Volume44
Issue number6
DOIs
StatePublished - 1966
Externally publishedYes

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