Iron-assisted oxidative radical C-C bond cleavage

Laurent Bénisvy; Jean Claude Chottard; Jérôme Marrot; Yun Li

doi:10.1002/ejic.200400782

Iron-assisted oxidative radical C-C bond cleavage

Laurent Bénisvy, Jean Claude Chottard, Jérôme Marrot, Yun Li

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

The N₂SO ligand, bis(N-methylimidazol-2-yl)-2-methylthio-ethanol (L), when coordinated to Fe³⁺ or Fe²⁺, undergoes a radical C-C bond cleavage in air, to form bis(N-methylimidazol-2-yl) ketone (Me₂-BIK).

Original language	English
Pages (from-to)	999-1002
Number of pages	4
Journal	European Journal of Inorganic Chemistry
Issue number	6
DOIs	https://doi.org/10.1002/ejic.200400782
State	Published - 18 Mar 2005
Externally published	Yes

Keywords

Imidazole ligand
Iron
Multidentate ligand
Radical fragmentation
Thioether ligand
X-ray diffraction

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10.1002/ejic.200400782

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title = "Iron-assisted oxidative radical C-C bond cleavage",

abstract = "The N2SO ligand, bis(N-methylimidazol-2-yl)-2-methylthio-ethanol (L), when coordinated to Fe3+ or Fe2+, undergoes a radical C-C bond cleavage in air, to form bis(N-methylimidazol-2-yl) ketone (Me2-BIK).",

keywords = "Imidazole ligand, Iron, Multidentate ligand, Radical fragmentation, Thioether ligand, X-ray diffraction",

author = "Laurent B{\'e}nisvy and Chottard, {Jean Claude} and J{\'e}r{\^o}me Marrot and Yun Li",

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AU - Bénisvy, Laurent

AU - Chottard, Jean Claude

AU - Marrot, Jérôme

AU - Li, Yun

PY - 2005/3/18

Y1 - 2005/3/18

N2 - The N2SO ligand, bis(N-methylimidazol-2-yl)-2-methylthio-ethanol (L), when coordinated to Fe3+ or Fe2+, undergoes a radical C-C bond cleavage in air, to form bis(N-methylimidazol-2-yl) ketone (Me2-BIK).

AB - The N2SO ligand, bis(N-methylimidazol-2-yl)-2-methylthio-ethanol (L), when coordinated to Fe3+ or Fe2+, undergoes a radical C-C bond cleavage in air, to form bis(N-methylimidazol-2-yl) ketone (Me2-BIK).

KW - Imidazole ligand

KW - Iron

KW - Multidentate ligand

KW - Radical fragmentation

KW - Thioether ligand

KW - X-ray diffraction

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DO - 10.1002/ejic.200400782

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JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

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ER -

Iron-assisted oxidative radical C-C bond cleavage

Abstract

Keywords

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