Interpolymer complexes of poly(acrylic acid) nanogels with some non-ionic polymers in aqueous solutions

Zauresh S. Nurkeeva; Vitaliy V. Khutoryanskiy; Grigoriy A. Mun; Asem B. Bitekenova; Slawomir Kadlubowski; Yulia A. Shilina; Piotr Ulanski; Janusz M. Rosiak

doi:10.1016/j.colsurfa.2004.01.026

Interpolymer complexes of poly(acrylic acid) nanogels with some non-ionic polymers in aqueous solutions

Zauresh S. Nurkeeva, Vitaliy V. Khutoryanskiy, Grigoriy A. Mun, Asem B. Bitekenova, Slawomir Kadlubowski, Yulia A. Shilina, Piotr Ulanski, Janusz M. Rosiak

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

Formation of interpolymer complexes (IPC) between the nanogels of poly(acrylic acid) (PAA) and linear polyvinylpyrrolidone (PVP), poly(vinyl methyl ether) (PVME) and poly(vinyl ether of ethyleneglycol) (PVEEG) in aqueous solutions has been studied by viscometric, turbidimetric and FTIR spectroscopic methods. It was found that in the course of complex formation the nanogels are characterised by lower amplitude of conformation changes in comparison with linear PAA. The critical pH values of complexation were determined. It was shown that the nanogels have lower complexation ability than linear PAA with respect to non-ionic polymers because of steric reasons caused by intramolecular cross-linked structure.

Original language	English
Pages (from-to)	141-146
Number of pages	6
Journal	Colloids and Surfaces A: Physicochemical and Engineering Aspects
Volume	236
Issue number	1-3
DOIs	https://doi.org/10.1016/j.colsurfa.2004.01.026
State	Published - 1 Apr 2004
Externally published	Yes

Bibliographical note

Funding Information:
The authors acknowledge the financial support of the work by the International Atomic Energy Agency (IAEA Research Contract No. 11787/R0/ Regular Budget Fund) and by the State Committee for Scientific Research (Poland), Grant No. 3 T09B 053 19.

Funding

The authors acknowledge the financial support of the work by the International Atomic Energy Agency (IAEA Research Contract No. 11787/R0/ Regular Budget Fund) and by the State Committee for Scientific Research (Poland), Grant No. 3 T09B 053 19.

Funders	Funder number
International Atomic Energy Agency	11787/R0
Komitet Badań Naukowych	3 T09B 053 19

Keywords

Critical pH
Hydrogen bonding
Interpolymer complexes
Nanogels
Poly(acrylic acid)

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Nurkeeva, Z. S., Khutoryanskiy, V. V., Mun, G. A., Bitekenova, A. B., Kadlubowski, S., Shilina, Y. A., Ulanski, P., & Rosiak, J. M. (2004). Interpolymer complexes of poly(acrylic acid) nanogels with some non-ionic polymers in aqueous solutions. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 236(1-3), 141-146. https://doi.org/10.1016/j.colsurfa.2004.01.026

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abstract = "Formation of interpolymer complexes (IPC) between the nanogels of poly(acrylic acid) (PAA) and linear polyvinylpyrrolidone (PVP), poly(vinyl methyl ether) (PVME) and poly(vinyl ether of ethyleneglycol) (PVEEG) in aqueous solutions has been studied by viscometric, turbidimetric and FTIR spectroscopic methods. It was found that in the course of complex formation the nanogels are characterised by lower amplitude of conformation changes in comparison with linear PAA. The critical pH values of complexation were determined. It was shown that the nanogels have lower complexation ability than linear PAA with respect to non-ionic polymers because of steric reasons caused by intramolecular cross-linked structure.",

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note = "Funding Information: The authors acknowledge the financial support of the work by the International Atomic Energy Agency (IAEA Research Contract No. 11787/R0/ Regular Budget Fund) and by the State Committee for Scientific Research (Poland), Grant No. 3 T09B 053 19.",

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AU - Nurkeeva, Zauresh S.

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AU - Mun, Grigoriy A.

AU - Bitekenova, Asem B.

AU - Kadlubowski, Slawomir

AU - Shilina, Yulia A.

AU - Ulanski, Piotr

AU - Rosiak, Janusz M.

N1 - Funding Information: The authors acknowledge the financial support of the work by the International Atomic Energy Agency (IAEA Research Contract No. 11787/R0/ Regular Budget Fund) and by the State Committee for Scientific Research (Poland), Grant No. 3 T09B 053 19.

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Interpolymer complexes of poly(acrylic acid) nanogels with some non-ionic polymers in aqueous solutions

Abstract

Bibliographical note

Funding

Keywords

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