Intermolecular metal transfer reactions and metal hydride shift isomerizations in (cycloheptatriene)tricarbonyliron derivatives

Zeev Goldschmidt; Yitzhak Bakal; Dorrit Hoffer; Amihai Eisenstadt; Peter F. Lindley

doi:10.1016/0022-328x(83)89507-2

Intermolecular metal transfer reactions and metal hydride shift isomerizations in (cycloheptatriene)tricarbonyliron derivatives

Zeev Goldschmidt
, Yitzhak Bakal
, Dorrit Hoffer
, Amihai Eisenstadt
, Peter F. Lindley

Department of Chemistry

Bar-Ilan University
Birkbeck University of London

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Upon heating, tricarbonyl[(3,4,5,6-η)-1-ethenyl-1,3,5-cycloheptatriene]iron derivatives Fe(CO)₃C₇H₇CHCHR (R COOMe, COC₆H₄OMe-p) gave the corresponding hexacarbonyl di-iron complexes. Under the same conditions the phenyl derivative (R C₆H₅) gave a mixture of a binuclear complex and the metal hydride shift isomer. The anti configuration of the binuclear complexes was established by X-ray crystallography.

Original language	English
Pages (from-to)	53-62
Number of pages	10
Journal	Journal of Organometallic Chemistry
Volume	258
Issue number	1
DOIs	https://doi.org/10.1016/0022-328x(83)89507-2
State	Published - 22 Nov 1983

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title = "Intermolecular metal transfer reactions and metal hydride shift isomerizations in (cycloheptatriene)tricarbonyliron derivatives",

abstract = "Upon heating, tricarbonyl[(3,4,5,6-η)-1-ethenyl-1,3,5-cycloheptatriene]iron derivatives Fe(CO)3C7H7CHCHR (R COOMe, COC6H4OMe-p) gave the corresponding hexacarbonyl di-iron complexes. Under the same conditions the phenyl derivative (R C6H5) gave a mixture of a binuclear complex and the metal hydride shift isomer. The anti configuration of the binuclear complexes was established by X-ray crystallography.",

author = "Zeev Goldschmidt and Yitzhak Bakal and Dorrit Hoffer and Amihai Eisenstadt and Lindley, \{Peter F.\}",

year = "1983",

month = nov,

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doi = "10.1016/0022-328x(83)89507-2",

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journal = "Journal of Organometallic Chemistry",

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T1 - Intermolecular metal transfer reactions and metal hydride shift isomerizations in (cycloheptatriene)tricarbonyliron derivatives

AU - Goldschmidt, Zeev

AU - Bakal, Yitzhak

AU - Hoffer, Dorrit

AU - Eisenstadt, Amihai

AU - Lindley, Peter F.

PY - 1983/11/22

Y1 - 1983/11/22

N2 - Upon heating, tricarbonyl[(3,4,5,6-η)-1-ethenyl-1,3,5-cycloheptatriene]iron derivatives Fe(CO)3C7H7CHCHR (R COOMe, COC6H4OMe-p) gave the corresponding hexacarbonyl di-iron complexes. Under the same conditions the phenyl derivative (R C6H5) gave a mixture of a binuclear complex and the metal hydride shift isomer. The anti configuration of the binuclear complexes was established by X-ray crystallography.

AB - Upon heating, tricarbonyl[(3,4,5,6-η)-1-ethenyl-1,3,5-cycloheptatriene]iron derivatives Fe(CO)3C7H7CHCHR (R COOMe, COC6H4OMe-p) gave the corresponding hexacarbonyl di-iron complexes. Under the same conditions the phenyl derivative (R C6H5) gave a mixture of a binuclear complex and the metal hydride shift isomer. The anti configuration of the binuclear complexes was established by X-ray crystallography.

UR - https://www.scopus.com/pages/publications/48749147707

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SN - 0022-328X

VL - 258

SP - 53

EP - 62

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Intermolecular metal transfer reactions and metal hydride shift isomerizations in (cycloheptatriene)tricarbonyliron derivatives

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