Intermolecular metal transfer reactions and metal hydride shift isomerizations in (cycloheptatriene)tricarbonyliron derivatives

Zeev Goldschmidt, Yitzhak Bakal, Dorrit Hoffer, Amihai Eisenstadt, Peter F. Lindley

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

Upon heating, tricarbonyl[(3,4,5,6-η)-1-ethenyl-1,3,5-cycloheptatriene]iron derivatives Fe(CO)3C7H7CHCHR (R COOMe, COC6H4OMe-p) gave the corresponding hexacarbonyl di-iron complexes. Under the same conditions the phenyl derivative (R C6H5) gave a mixture of a binuclear complex and the metal hydride shift isomer. The anti configuration of the binuclear complexes was established by X-ray crystallography.

Original languageEnglish
Pages (from-to)53-62
Number of pages10
JournalJournal of Organometallic Chemistry
Volume258
Issue number1
DOIs
StatePublished - 22 Nov 1983

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