TY - JOUR
T1 - Interfacial electrodeposition of silver
AU - Zeiri, L.
AU - Younes, O.
AU - Efrima, S.
AU - Deutsch, M.
PY - 1997/11/6
Y1 - 1997/11/6
N2 - A systematic study of silver ion electrodeposition at the water/air and water/dichloromethane interfaces, under potentiostatic control, is presented. We study the morphology of the deposits and their growth rate, as a function of several important physical and chemical parameters, namely, the electric voltage, the silver ion concentration, the conductivity, the viscosity, and the presence of a surfactant and an organic anionic additive known to associate with silver. The results are discussed in terms of a generalized Wagner number, which is shown to correlate well with the observations and to be a highly reliable predictive tool for the morphologies.
AB - A systematic study of silver ion electrodeposition at the water/air and water/dichloromethane interfaces, under potentiostatic control, is presented. We study the morphology of the deposits and their growth rate, as a function of several important physical and chemical parameters, namely, the electric voltage, the silver ion concentration, the conductivity, the viscosity, and the presence of a surfactant and an organic anionic additive known to associate with silver. The results are discussed in terms of a generalized Wagner number, which is shown to correlate well with the observations and to be a highly reliable predictive tool for the morphologies.
UR - http://www.scopus.com/inward/record.url?scp=0031556660&partnerID=8YFLogxK
U2 - 10.1021/jp971772t
DO - 10.1021/jp971772t
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AN - SCOPUS:0031556660
SN - 1520-6106
VL - 101
SP - 9299
EP - 9308
JO - Journal of Physical Chemistry B
JF - Journal of Physical Chemistry B
IS - 45
ER -